Zanotto ED

Vitreous Materials Lab.
LaMaV
DEMa - UFSCar
lamav.weebly.com
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Desafios...
• Adversidades despertam capacidades que, em outras
circunstâncias, teriam ficado adormecidas...
• Estranhamente o Homem somente progride perante
um ambiente desafiador. Se consegue, passo a passo,
superar seus desafios, fica feliz e com mais energia e
vontade de tentar novas soluções e novos projetos.
Fica divertido!
Edgar Dutra Zanotto
Center For Research, Technology and
Education in Vitreous Materials
CeRTEV´s activities will focus on
multidisciplinary, relevant glass science, useful
technology and efficient education and outreach!
SCOPE
CeRTEV will research and develop or improve glasses and glass-ceramics
presenting application-relevant functionalities, such as high mechanical strength
and electrical conductivity, biological, optical or catalytic activity, and/or
combinations of these properties.
A fundamental understanding of these properties will be sought on the basis of
the structural organization of these materials on different length scales. We will
apply state-of-the art NMR, EPR, EXAFS and vibrational spectroscopy to
characterize the local and medium-range order, as well as the full resolution
range of optical and electron microscopies, XRD and microanalyses for
elucidating nano- and microstructures. This comprehensive experimental
approach will be complemented by molecular dynamics simulations.
Using this experimental modeling strategy, we will further seek a fundamental
understanding of glass sintering and crystallization in terms of the mechanisms,
thermodynamics and kinetics of viscous flow, as well as crystal nucleation and
growth, enabling us to exercise control of these processes by developing
appropriate formation and thermal treatment protocols.
In a concerted effort, the participating laboratories will jointly investigate a
number of important benchmark systems, which are deemed particularly
promising for applications either as structural materials (e.g., dental and armor
glass-ceramics), bio active glasses and glass-ceramics, glass-ceramics for
architecture and construction, optical materials (e.g., laser glasses), materials for
electrochemical energy storage devices (electrolytes, high-temperature seals),
and catalytically active systems.
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Glass-ceramics
Dental
Construction
Gratings
Coordinador
Tech &
Innovation
Director
Coordinator
Education and
Outreach
Manager
2 secretaries
1 informatics
Vice-director
14 professors FQV
~30 collaborators
~60 students
One of the largest academic glass R & D
of this planet!
The Team 14
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Leandro Innocentini L. de Faria,
Manager, Scientometry
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STRUCTURE
Hellmut Eckert
José Fabián Schneider
Claudio José Magon
Jose Pedro Donoso Gonzalez
Valmor Roberto Mastelaro
Paulo Sergio Pizani
José Pedro Rino
Structure, NMR
Structure, NMR
EPR
EPR
EXAFS, XRD and laser crystallization
Raman spectroscopy
Molecular dynamics simulation
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CRYSTALLIZATION + Thermal, Mechanical, Bio and Electrical properties
Edgar Dutra Zanotto
Nucleation, growth, crystallization , glass-ceramics
Marcello Rubens Barsi Andreeta Laser crystallization, crystal growth techniques
Ana Cândida Martins Rodrigues Electrical properties, ionic conducting glass & GC
Oscar Peitl
Bio active glasses and glass-ceramics
Eduardo Bellini Ferreira
Nucleation, growth, crystallization, glass-ceramics
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OPTICAL Properties
Andrea S. S. de Camargo Alvarez Bernardez
Marcelo Nalin
Optical properties
Optical and chemical properties
Ranking in the world (2013)
• A June 2013 search on the SCOPUS database for the
number of published articles with relevant keywords
indicates that some of CeRTEV´s faculty rank:
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first in the world with the keywords glass* and NMR*,
first with glass* and nucleation,
second with glass* and crystal growth,
fourth with glass* and crystallization,
26th with bio* and glass-ceramic*,
28thwith glass* and sinter*,
31th with glass-ceramic*,
43th with glass* and EXAFS.
Scientific papers - Ranking 1829-2013
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Russian Academy of Sciences(1,111 glass papers)
Kyoto University(849)
SCOPUS search
CeRTEV = USP(370)+ UNESP-(225)+ UFSCar (181) = 776
glass*+
Shanghai Institute of Optics and Fine Mechanics (759)
CNRS Centre National de la Recherche Scientifique(735)
vitreous+
Tokyo Institute of Technology(624)
amorphous+
University of Cambridge(574)
non-crystalline University of Tokyo(553)
Osaka University(550)
( metal* and polymer*)
The State Scientific-Research Institute of Glass(550)
Friedrich Schiller Universität Jena(479)
Universite Pierre et Marie Curie(471)
Chinese Academy of Sciences(457)
Corning Incorporated(445)
Alcatel-Lucent Bell Labs(432)
Pennsylvania State University(426)
Argonne National Laboratory(423)
Massachusetts Institute of Technology(412)
S.I. Vavilov State Optical Institute(393)
National Institute of Advanced Industrial Science and Technology(383)
Universite de Rennes 1(375)
22th USP(370)
Consiglio Nazionale delle Ricerche(366)
Universite Montpellier 2 Sciences et Techniques(363)
Indian Institute of Science(361)
Hokkaido University(358)
University of Sheffield(351)
Alfred University(343)
Kyushu University(341)
Ranking 2010-2013
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Shanghai Institute of Optics and Fine Mechanics CAS(201)
Russian Academy of Sciences(177)
CeRTEV = USP(67)+UFSCar(48)+UNESP(43) = 158
Ningbo University(152)
Graduate University of Chinese Academy of Sciences(142)
CNRS Centre National de la Recherche Scientifique(137)
South China University of Technology(107)
Wuhan University of Technology(104)
Chinese Academy of Sciences(101)
Universite de Rennes 1(96)
University of Tokyo(94)
Friedrich Schiller Universität Jena(93)
Harbin Institute of Technology(91)
Sri Venkateswara University(85)
Universite Pierre et Marie Curie(82)
Kyoto University(82)
Tongji University(82)
National Research Center, Cairo(79)
University of Pardubice(78)
Sichuan University(77)
Consiglio Nazionale delle Ricerche(75)
Tohoku University(72)
Osaka University(72)
East China University of Science and Technology(71)
Pacific Northwest National Laboratory(71)
Tokyo Institute of Technology(71)
Universität Erlangen-Nürnberg(69)
Shanghai Institute of Ceramics Chinese Academy of Sciences(69)
Tsinghua University(68)
30th Universidade de Sao Paulo(67)
Corning Incorporated(62)
glass*+
vitreous+
amorphous+
non-crystalline (metal* and polymer*)
Budget
~US$ 20 million from Fapesp for
equipament, travel, materials and
supplies spread over 11 years
(excluding salaries and students grants)
But Fapesp expects us to get
complementary funding from other
government agencies and industries...
International Advisory Board
• GOMD meeting, San Diego, June 2013
• Fran Serbena, Dick Brow, Bruce Aitken and Ed
Zanotto.
• Credit ACerS
ICG, Prague, July 2013
Our philosophy
 To pursue relevant research topics with well defined
objectives.
 To carry out long term basic research. To reach and
expand the frontiers of knowledge in each one of the
chosen subjects.
 Maximize planning, calculation, simulation, literature
search and study to optimize experimentation.
 To publish original, accurate articles that push the
frontiers of knowledge. Quality, and not quantity, is
our goal.
 Technological research via industrial interest that may
lead to patents and eventually innovation
New glass research center in Brazil
2 universities, 14 profs, 11 years, $20 M
—one big impact!
Published on July 8th, 2013
by Eileen De Guire
The American Ceramic Society
Jena
1982
Russel
Grenoble
1984
Souquet
TC7 (1984)
IMI (2004)
J. Mauro
Corning
IVSO Inst.
1996
Univ. Rostock
2001
Fokin
Schmelzer
LaMaV´s
International
NETWORK
J. Du
Univ. Texas
Starting
in 2014
CeRTEV
2012
Erlangen
2003
Boccaccini
Bio glass and GC
~15 institutions
L. Hench, Boccacini
Rocherullè &
Rouxel
Rennes
J. Lumeau
Fresnel
Selected papers published in 2013
Structure of vitreous materials
Ren, J., Eckert, H., Anion distribution in superionic Ag3PO4-AgI glasses revealed by dipolar solid-state
NMR, Journal of Physical Chemistry C 117 (47), pp. 24746-24751, 2013.
Schneider, J., Tsuchida, J., Eckert, H., Cation size effects in mixed-ion metaphosphate glasses: Structural
characterization by multinuclear solid state NMR spectroscopy, Physical Chemistry Chemical Physics 15
(34), pp. 14328-14339,2013.
DQ-DRENAR: a New NMR Technique to Measure Site-Resolved Magnetic Dipole-Dipole Interactions in
Multispin-1/2 Systems. Theory and Applications to Phosphate Materials, Ren,J.; Eckert, H. J. Chem. Phys.
138, 164201/1-16 (2013).
Sol-Gel preparation and structural characterization of mesoporous Al2O3-SiO2 glasses, Ren, J.; Zhang,
L.; Eckert, H. Sol Gel Sci Technol. 2014, in press.
Medium range order in sol-gel prepared Al2O3-SiO2 glasses: New results from solid State NMR, Ren, J.;
Zhang, L; Eckert, H. J. Phys. Chem. C 2014, in press.
Pontes, D.S.L.; Pontes, F.M.; da Silva, L.F.; Chiquito, A.J.; Pizani, P.S.; Longo, E. Influence of a cosubstituted A-site on structural characteristics and ferroelectricity of (Pb, Ba, Ca)TiO3 complex perovskites:
analysis of local-, medium- and long-range order. Journal of Sol-Gel Sci Technology, pp. 1-12. 2014.
Crystal Nucleation, Growth and Overall Crystallization
Fokin, V.M.; Reis, R.M.C.V.; Abyzov, A.S.; Chinaglia, C.R.; Zanotto, E.D. Nonstoichiometric
crystallization of lithium metasilicate-calcium metasilicate glasses. Part 1 - Crystal nucleation and
growth rates. Journal of Non-Crystalline Solids 362 (1), pp. 56-64. 2013.
Fokin, V.M.; Reis, R.M.C.V.; Abyzov, A.S.; Chinaglia, C.R.; Schmelzer, J.W.P.; Zanotto, E.D. Nonstoichiometric crystallization of lithium metasilicate-calcium metasilicate glasses. Part 2 - Effect of
the residual liquid. Journal of Non-Crystalline Solids 379, pp. 131-144. 2013.
Cabral, A.A.; Ferreira, E.B.; Villas-Boas, M.O.C.; Zanotto, E.D. On the determination of the
concentration of crystal nuclei in glasses by DSC. Journal of the American Ceramic Society 96
(9), pp. 2817-2823. 2013.
Dyamant, I.; Abyzov, A.S.; Fokin, V.M.; Zanotto, E.D.; Lumeau, J.; Glebova, L.N.; Glebov, L.B.
Crystal nucleation and growth kinetics of NaF in photo-thermo-refractive glass. Journal of NonCrystalline Solids 378, pp. 115-120. 2013.
Zanotto, E.D. Glass Crystallization Research - A 36-Year Retrospective. Part I, Fundamental
Studies. International Journal of Applied Glass Science 4 (2), pp. 105-116. 2013.
Rodrigues, A.M.; Narváez-Semanate, J.L.; Cabral, A.A.; Rodrigues, A.C.M. Determination of
crystallization kinetics parameters of a Li1.5Al0.5Ge1.5(PO4)3 (LAGP) glass by differential
scanning calorimetry. Materials Research 16 (4) 2013.
Jasinevicius, R.G.; Duduch, J.G.; Pizani, P.S. Evidence of crystallographic orientation
dependence upon cyclic microindentation-induced recrystallization within amorphous surface
layer. Materials Letters 94, pp. 201-205. 2013.
Almeida, J.M.P., Tribuzi, V., Fonseca, R.D., Otuka, A.J.G., Ferreira, P.H.D., Mastelaro, V.R.,
Brajato, P., Hernandes, A.C., Dev, A., Voss, T., Correa, D.S., Mendonca, C.R., Femtosecond laser
processing of glassy and polymeric matrices containing metals and semiconductor
nanostructures, Optical Materials 35 (12), pp. 2643-2648, 2013.
Bioactive glasses and glass-ceramics
Souza, M.T.; Crovace, M.C.; Schröder, C.; Eckert, H.; Peitl, O.; Zanotto, E.D. Effect of magnesium ion incorporation on
the thermal stability, dissolution behavior and bioactivity in Bioglass-derived glasses. Journal of Non-Crystalline Solids 382,
pp. 57-65. 2013.
Renno, A.C.M.; Bossini, P.S.; Crovace, M.C.; Rodrigues, A.C.M.; Zanotto, E.D.; Parizotto, N.A. Characterization and in
vivo biological performance of biosilicate. BioMed Research International 2013, art. no. 141427. 2013.
Renno, A.C.M.; Nejadnik, M.R.; Van De Watering, F.C.J.; Crovace, M.C.; Zanotto, E.D.; Hoefnagels, J.P.M.; Wolke,
J.G.C.; Jansen, J.A.; Van Den Beucken, J.J.J.P. Incorporation of bioactive glass in calcium phosphate cement: Material
characterization and in vitro degradation. Journal of Biomedical Materials Research - Part A 101 A (8), pp. 2365-2373.
2013.
Desimone, D.; Li, W.; Roether, J.A.; Schubert, D.W.; Crovace, M.C.; Rodrigues, A.C.M.; Zanotto, E.D.; Boccaccini, A.R.
Biosilicate®-gelatine bone scaffolds by the foam replica technique: Development and characterization. Science and
Technology of Advanced Materials 14 (4), art. no. 045008. 2013.
Pinto, K.N.Z.; Tim, C.R.; Crovace, M.C.; Matsumoto, M.A.; Parizotto, N.A.; Zanotto, E.D.; Peitl, O.; Rennó, A.C.M. Effects
of biosilicate® scaffolds and low-level laser therapy on the process of bone healing. Photomedicine and Laser Surgery 31
(6), pp. 252-260. 2013.
Renno, A.C.M.; Van De Watering, F.C.J.; Nejadnik, M.R.; Crovace, M.C.; Zanotto, E.D.; Wolke, J.G.C.; Jansen, J.A.; Van
Den Beucken, J.J.J.P. Incorporation of bioactive glass in calcium phosphate cement: An evaluation. Acta Biomaterialia 9
(3), pp. 5728-5739. 2013.
Kido, H.W.; Oliveira, P.; Parizotto, N.A.; Crovace, M.C.; Zanotto, E.D.; Peitl-Filho, O.; Fernandes, K.P.S.; MesquitaFerrari, R.A.; Ribeiro, D.A.; Renno, A.C.M. Histopathological, cytotoxicity and genotoxicity evaluation of Biosilicate® glassceramic scaffolds. Journal of Biomedical Materials Research - Part A 101 A (3), pp. 667-673. 2013.
Siqueira, R.L.; Zanotto, E.D. The influence of phosphorus precursors on the synthesis and bioactivity of SiO2-CaO-P2O5
sol-gel glasses and glass-ceramics. Journal of Materials Science: Materials in Medicine 24 (2), pp. 365-379. 2013.
Daguano, J.K.M.F., Rogero, S.O.,Crovace, M.C., Peitl, O., Strecker, K.,Dos Santos, C., Bioactivity and cytotoxicity of glass
and glass-ceramics based on the 3CaO•P2O5-SiO2-MgO system, ournal of Materials Science: Materials in Medicine 24
(9), pp. 2171-2180, 2013.
Brandão, S.M., Schellini, S.A.,Padovani, C.R., Peitl, O., Hashimoto, E., Análise da biocompatibilidade de cones de
biovidro e biovitrocerâmico (Biosilicato®) em cavidade eviscerada de coelho | [Biocompatibility analisys of Bioglass® 45S5
Other types of glass-ceramics
Zanotto, E.D. Glass Crystallization Research - A 36-Year
Retrospective. Part II, Methods of Study and GlassCeramics. International Journal of Applied Glass Science 4
(2), pp. 117-124. 2013.
Soares, V.O.; Peitl, O.; Zanotto, E.D. New sintered Li2O Al2O3- SiO2 ultra-low expansion glass-ceramic. Journal of
the American Ceramic Society 96 (4), pp. 1143-1149. 2013.
Kjeldsen, J.; Yue, Y.; Bragatto, C.B.; Rodrigues,
A.C.M. Electronic conductivity of vanadium-tellurite glassceramics. Journal of Non-Crystalline Solids 378, pp. 196200. 2013.
Optical Properties
De Queiroz, T.B., Botelho, M.B.S., De Boni, L., Eckert, H., De Camargo,
A.S.S., Strategies for reducing dye aggregation in luminescent host-guest
systems: Rhodamine 6G incorporated in new mesoporous sol-gel hosts,
Journal of Applied Physics 113 (11) , art. no. 113508, 2013.
De Queiroz, T.B., Botelho, M.B.S., Fernández-Hernández, J.M., Eckert,
H., Albuquerque, R.Q., De Camargo, A.S.S., New luminescent hostguest system based on an iridium(III) complex: Design, synthesis, and
theoretical-experimental spectroscopic characterization, Journal of
Physical Chemistry C 117 (6), pp. 2966-2975, 2013.
Santos, W.Q., De Camargo, A.S.S.,Wu, D., Silva, W.F., Zhang, L.,
Jacinto, C., Cooperative upconversion, radiation trapping, and selfquenching effects in highly Yb3+-doped oxyfluoride glasses, Science of
Advanced Materials 5 (12) , pp. 1948-1953, 2013.
Optical Properties
Manzani, D.; Almeida, J.M.P.; Napoli, M.; De Boni, L.; Nalin, M.; Afonso,
C.R.M.; Ribeiro, S.J.L.; Mendonça, C.R. Nonlinear optical properties of tungsten
lead-pyrophosphate glasses containing metallic copper
Nanoparticles. Plasmonics 8 (4), pp. 1667-1674. 2013.
Valle, P.S.; Montesso, M.; Nalin, M.; Donoso, J.P.; Silva, I.D.A.; Magon,
C.J. Influence of silver precursors on growth of metallic nanoparticles in heavy
metal oxide glasses. Quimica Nova 36 (7), pp. 967-971, 2013.
Avila, L.F.; Almeida, J.M.P.; Gonçalves, M.S.; Valle, P.S.; Nalin, M.; Mendonça,
C.R.; Cescato, L. Design and fabrication of two-dimensional hexagonal photonic
crystals with a linear waveguide in erbium doped GeO2-Bi2O 3-PbO-TiO2
glasses. Proceedings of SPIE - The International Society for Optical
Engineering 8776, art. no. 87760L, 2013.
Avila, L.F.; Nalin, M.; Cescato, L. Self diffraction holographic techniques for
investigation of photosensitive materials. Proceedings of SPIE - The
International Society for Optical Engineering 8776, art. no. 87760G, 2013.
Book Chapters
Glasses on the Nanoscale, Eckert, H. Ribeiro, S.J.L.; Santagneli, S. H.; Nalin,
M.; Poirier, G.; Messaddeq,Y. Handbook of Nanomaterials, R. Vajtai, ed. SpringerVerlag Berlin, 665-692 (2013).
Advanced NMR Spectroscopy of Glasses (Review), Eckert, H. to be published in
“Modern Glass Characterization”, M. Affatigato, ed., John Wiley and Sons 2014.
Bioactive Glass-Ceramics for Load-Bearing Applications - Oscar Peitl, Edgar D
Zanotto, Francisco C Serbena and Larry L Hench) - “An Introduction to
Bioceramics”, 2nd Edition Edited by: L. L. Hench, ed., World Scientific (2013)
Zanotto E.D. et al- DSC techniques for the study of glass crystallization, in
“Glassy, Amorphous and Nano-Crystalline Materials” ed. J. Sestak, J. Mares, P.
Hubik , Springer (2013)
Nucleation, Growth and Overall Crystallization, Zanotto, E.D et al., to be published
in “Glass Encyclopedia” , P. Richet, ed., John Wiley and Sons 2014
Stress-induced Pore Formation and Phase Selection in a Crystallizing Stretched
Glass, Fokin V.M., Karamanov A., Abyzov A.S, Schmelzer J. W.P., Zanotto E.D,
Chapt.8 to be published in “Glass: Selected Properties and Crystallization”, J.
Schmelzer, ed., De Gruyter 2014
Planned books
• Crystals in glass – Wiley, Oct. 2013
. Experimental techniques for characterization
glass structure and crystallization - start 2014
(CeRTEV team)
• Fundamentals of glass crystallization start
2014
(Zanotto, Fokin & Schmelzer)
Internationalization
Visiting professors in 2013
Vladimir Fokin – St. Petersburg, Russia, one year
Jean Louis Souquet- Grenoble, France, 6 months
Juern Schmelzer, Rostok, Germany, 1 week
Alexander Priven, Korea, 1 week
Post-docs and students
2 undergrads from the USA
2 MSc students from Colombia
1PhD student from Iran (sanduiche)
2 post-docs from India
Organization of Congresses, etc...
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Internal workshops – yearly starting 2013
Invention & Innovation – Sept. 2013
Sol-gel workshop – Oct. 2013
Rede BioNetec Meetings – yearly starting Nov. 2013
• X Brazilian Symposium on Glass – Oct. 2014
• São Paulo School on Glasses and CG – Feb. 2015
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Education and Outreach about glass – 2015
Flow and Fracture in Glass – 2016 (?)
XI Brazilian Symposium on Glass – 2017
“Glass frontiers” jointly with the World Congress of
Ceramics, Iguassu Falls - 2018
Invited talks 2013
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Hellmut Eckert
A homonuclear version of REDOR for recoupling dipolar interactions in multi-spin systems:
Applications to inorganic phosphorus clusters and networks, International Symposium of
Magnetic Resonance (ISMAR), Rio de Janeiro, May 2013.(Invited)
Introduction into Solid State NMR Spectroscopy, workshop, SBQ meeting, Aguas Lindoias, May
2013. (Invited)
Modern Solid State NMR Strategies for Studying Structural Transformations in Non-Siliceous
Sol-Gel – Glass Systems, SBPMAT, Campos de Jordão, September 2013.(Invited)
Ed Zanotto
Iron Phosphate Glasses and Melts - A US-Brazil Research Collaboration on Novel Materials
for Nuclear Waste Remediation - 37th International Conference & Exposition on Advanced
Ceramics & Composites, Daytona Beach, USA, Jan. 24-28, 2013 (delivered by R.K.
Brow) (Invited)
The relationship between molecular structure and nucleation mechanism in glass, ICG 2013,
Prague Czech Republic, July 1-6 2013 (Invited)
LaMaV/ UFSCar - 36 anos de ensino, ciência e inovação - II Workshop UEPG, Ponta Grossa,
PR, August 13-14, 2013 (Opening Talk)
LaMaV – UFSCar / 36 anos interagindo com empresas, 22 Encontro Técnico da ABIVIDRO, São
Paulo, Oct. 2, 2013 (Invited)
Advances in glass crystallization and glass-ceramics- 19th Larson Workshop on Crystallization
Technology, Indianapolis, USA, October 5-10, 2013 (Invited)
36 years of science, technology and art - Magna lecture - Admiral Álvaro Alberto Award cerimony
- CNPq, Brasília, October 23 , 2013 (Invited)
Vitrocerâmicas - passado, presente e futuro - Workshop CEFET, São Luiz, MA, 3 Nov.
2013 (Invited)
LaMaV - 3,5 décadas de invenções. Aprendendo com os erros - I EEAEM, UFSCar, 28
Nov. 2013 (Invited)
J. P. Rino
Editorship of periodicals
-Solid State Nuclear Magnetic Resonance
Hellmut Eckert – Editor
-Journal of Non-Crystalline Solids
Edgar D. Zanotto - Editor
-Int. Journal of Applied Glass Science, USA- IAB
-Materials Research, Brazil - IAB
-Ceramica y Vidrio, Spain - IAB
-Cerâmica, Brazil – IAB
-The Open Crystallography Journal –
Marcello R. Barsi Andreeta - Associate Editor
Technology
Coordinator – Prof. Eduardo B. Ferreira,
EESC- USP
O-I TAB meeting,
Perrysburg, USA, March 2014
• Review and make recommendations on
O-I´s technology portfoglio
• EDZ´s talk about CeRTEV
Glassman South America , March 2014
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9h30 Opening Show: Glassman South America
Lucien Belmonte / Greg Morris Abividro
9h40 Cleanfire GC
Edson E. Basilio
Air Products
10h
Heat Recovery
Fabio Guastini
Area Impianti
10h20 New cost efficient solution for glass moulds
Sergio Simones
Hoganas
10h40 Hot Bottom Repair
Cristina Sanches
Fosbel
11h
New Material for Glass Melting Eletrodes
Elisio Ferreira Neto
Plansee
11h20 Defeitos no vidro vs. refratários
Marcelo Guerra
SEFPRO
1h20 An introduction to the FleXinspect
Michael G. Rentschler Buch Emhart Glass
1h40 Glass Sand
Manoel J. B. Cordova Mineração Jundu
2h
Inovation on glass packaging
Daniel Amaral
OI
2h20 Soda-ash
Tarcisio Neves /Walter Shultz (ANSAC)
2h40 Brazilian Climate Changes
Stefan David
Abividro
3h
Oxygen Enhanced Nox Reduction
Abilio Tasca
Praxair – White
3h20 Quality Control of Cullet
Marcos Gibim
Verallia – CETEV
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9h40
10h
10h20
10h40
Made in Germany for Glass People
K. Rudolph
GPS - Verallia
Speedline - Evolution in IS machines
Rainer Heidemann
Heye International
Brazilian Law on Wastes
Ana Paula Bernardes Abividro
CeRTEV- Center for Research, Technology and Education in Vitreous Materials
Edgar Zanotto
CeRTEV/UFSCar
Corning Inc. Research Summit,
Corning, USA June 2014
• EDZ talk
Vitrovita & DMC, Brazil
bioG and CG
Optigrate, USA
PTRG
NSG, Japan
viscous flow
CTA, Brazil
Armor GC
Corning, USA
GR Status & trends
AGY, USA
special fibers
LaMaV
industry net
Ivoclar?
Dental GC
Neogres?
sintered G & GC
Saxon Glass?
chem. tough
Current projects with companies
 Ongoing
 GC Armors, CTA, Brazil
 Bioactive GC for dental and medical use – Vitrovita /
DMC, Brazil
 Photo-thermo-crystallization PTRG – OptiGrate, USA
 Viscous flow and crystal growth in glasses, NSG, Japan
 Special glass fibers , AGY, USA
 Glass containers , O-I, USA
 In negociation
 Dental GC - Ivoclar, Liechtenstein (NDA signed)
 LGLT GC – Phillips, Netherlands (testing)
 Chemically toughened glass- Saxon Glass, USA (neg.)
 Sintered GC / GC tiles - UNIGRES, Brazil (negociation)
Example - Bio G and GC technologies
being developed
Pós
Grânulos
Manta Flexível
Prótese Ocular
Prótese de Ouvido Médio
Implantes Recobertos
Scaffolds
Recent CeRTEV Patents
• Leo et al – Armor transparent GC (2013)
• Marina et al – New bioactive fiberizable GC (2013)
• Clever et al – Bioactive coating for Ti (2014)- deposited
• Marina et al – Fiber drawing machine (2014) • Zanotto et al.- “REFORMIX Glass - Software for
formulation of glass compositions having combined
properties” (2014)
• EDZ - The best putter in the world (2014)!
Education and Outreach
Discussion group / Brazilian glass researchers and
engineers – active
Kit for demonstration of optical phenomena for
undergraduate or high school students - ready
Colored glass kits - ready
Web-site with educational videos - ready
Virtual museum of glass (under construction)
EDUCATION AND OUTREACH
Creation of the first technical course in South
America
Being aware of the lack of professional
training course dedicated to the glass industry,
with the partnership of Paula Souza Center,
we proposed to create a technical course to
provide trained professionals for the glass
industry.
EDUCATION AND OUTREACH
What we have done so far:
First meeting: presentation of our project CeRTEV and Education and
outreach project to ABIVIDRO
Second Meeting: Joint meeting with ABIVIDRO and Paula Souza Center
- ABIVIDRO confirmed to Paula Souza Center the urgent need for
professional qualification, specially at technical level, to the glass industry.
Paula Souza Center asked to describe all technical positions (cargos
técnicos)
Third meeting: we described the technical positions for the glass (flat and
hollow ) fabrication , glass transformation, and also glass specification for
construction
Next step: a memorandum of agreement between ABIVIDRO, Paula
Souza Center and CeRTEV, aiming the consolidation of this new technical
course must be prepared and signed
EDUCATION AND OUTREACH
Already done:
-ACIEPE: Engineers and Scientists of the Future - UFSCar
program aiming to demonstrate to elementary school students of
São Carlos the basis of “scientific thinking”, aiming to attract them
to the field of engineering and hard sciences.
-Meeting and agreement with the Secretary of Science and
Technology of São Carlos: participation in the program “Science
at School”
Same program with Araraquara
-School visits to LaMaV – glass melting, short talks and video
demonstrations to hundreds of high school students from all over
the State of São Paulo… (UFSCar open day and more…)
Plans for 2014-2015
-Offer the first class of the Paula Souza Center technical course in
2015
-Produce a video-course for architects about the fundamentals of
glasses and its specifications for architectural building.
-Create a collection of demonstrational functional glasses
such as: electrically conducting glass, fotosensitive (PTRG) glass,
invisible gass, optical fiber, thermal strain in glass, metallic glass,
sugar glass…
How to use these functional glasses outside our classroom?
Physical Museum – planed for 2015
São Paulo (International) School of Structure, Crystallization and
Properties of Glasses – planed for 2015
Aknowledgements
• São Paulo Research Foundation FAPESP
Grant # 2013/07199-6
LaMaV
37 years of equilibrium between
science & technology
Edgar D. Zanotto
LaMaV’s mission
 TO EDUCATE excellent engineers and researchers
via good research and teaching
 TO EXPAND the frontiers of knowledge /
via basic research / excellent publications!
 TO ASSIST companies beyond their expectations /
consulting + applied research
 TO INNOVATE in the field of glass and related
materials / via technological research
by
Sheffield
1979
P. James*
Jena
1982
C. Russel
Mastelaro/ Sneid, IFSC/ USP
P. C. Soares, UFPR
A. A. Cabral, CEFET, MA
E.B. Ferreira, EESC
J. Daguano- UFABC
F. Serbena e V.Soares - UEPG
Cyted/ CNPq, 1998
ICV - A. Duran
U. Medellin – C.
Paucar
ADEMAT, 2003
IC - A. Boccaccini
Max Plank –
A. Pyzalla
Grenoble
1984
J. L. Souquet
La MaV
NETWORK
Arizona
1987
M. Weinberg*
Florida
1994
L. Hench
Bio glass and GC
~15 instituições
Optigrade, NSG, AGY, Vitrovita,Saxon, CT
IVSO Institute
1996, V. M. Fokin
IMI
2004
TC 7 / ICG
1985
Clausthal
J. Deubener
2005
CNEA, 1998
M. Prado
CREOL/ UCF
L. Glebov
2005
BAM, 1999
R. Muller
UMR
R. Brow
2005
Bulg. Acad. Sci.
I. Avramov 2001
Univ. Rostock
J. Schmelzer 200
Douhausie
J. Zwanziger
2005
Bio glass and GC
~15 institutions
LaMaV´s
Brazilian
NETWORK
Daguano
UFABC
H.E., Mastelaro &
Schneider , Magon
IFSC
Ferreira
EESC
Soares
PUC-PR
CeRTEV
2012
Cabral
CEFET
Serbena &
Oliveira
UEPG e UEMA
TEAM
ANNUAL BUDGET
Permanent
E.D. Zanotto / Crystallization & thermo-mechanical properties
O. Peitl - Bio glasses/ Chemical and thermo-mechanical properties
A.C.M. Rodrigues / Electrical properties
1 technician (Zé)
...........................................
.............
US$ 430,000
Temporary
4 post docs
9 PhD students
2 MSc students
10 Internship students
1 secretary
Materials & Supplies
...........................................
400,000
..........................................
200,000
US$ 1,030,000.00
TOTAL NORMALIZED by PPP (1.0147/0.5336) ~2,000,000
Muito obrigado!
• Thank you very much!
• Vielen Dank!
• Dziękuję !
• Hjärtligt tack !
• Muchas gracias!
• Merci beaucoup!
• Grazie mille!
University Ranking 1937-2013
glass*+vitreous+amorphous+non-crystalline
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Tohoku University (1,660) + Tohoku University(1,287 ) Inoue’s
Kyoto University(1,265)
CeRTEV: USP (476) + UNESP (278) + UFSCar (275) = 1029
Osaka University(938)
Tokyo Institute of Technology(901)
University of Cambridge(855)
University of Tokyo(736)
Massachusetts Institute of Technology(686)
Friedrich Schiller Universität Jena(601)
Pennsylvania State University(600)
Universite Pierre et Marie Curie(572)
Tsinghua University(571)
University of Sheffield(525)
Stanford University(516)
California Institute of Technology(488)
MoskovskijGosudarstvennyjUniversitet(483)
Universite de Rennes 1(480)
USP (476)
Imperial College London(473)
Kyushu University(460)
Universite Montpellier 2 Sciences et Techniques(441)
Hokkaido University(433)
Nagoya University(430)
University of Science and Technology Beijing(403)
Wuhan University of Technology(403)
Alfred University(401)