Balistol - martin

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Balistol - martin

MATERIAL SAFETY DATA SHEET
Tradename:
Article No:
Issue:
ACCORDING TO . 2001/58/EG
MARTIN Ballistol Oil + Aerosol
HT00.0061
January 2010
Page 1 of 6
_____________________________________________________________________________________________________
1. Identification of the Substance / Preparation and of the Company
1.1
Identification of the Substance / Preparation
Ballistol Oil + Aerosol
1.2
Application of the Substance / Preparation
Maintainance, cleaning, cust prevention and Lubricating of metal parts.
1.3
Company/Undertaking Identification
MARTIN GmbH
Argelsrieder Feld 1b
D-82234 Wessling
Phone:
+49-8153-932 93-0
Fax:
+49-8153-932 93-9
www.martin-smt.de
1.4
Emergency Telephone
Please contact the nearest poison emergency center.
2. Composition of / Information on Ingredients
2.1
Chemical Characterisation
Rustpreventing and lubricating oil.
2.2
Hazardous Contents
Spray:
Propellent propane-butane (CAS-Nr. 74-98-6; 106-97-8)
Liquid Hydrocarbons (CAS-Nr. 64742-49-0).
2.3
Additional Information: 3. Hazards Identification
3.1
Classification
Oil:
R 10
Aersolol:
R 12
combustible in contact with open fire.
Highly inflammable.
4. First Aids Measures
4.1
Inhalation
Fresh air.
4.2
Skin Contact
-
4.3
Eye Contact
Rinse with water.
4.4
Ingestion
Not hazardous when ingested.
4.5
Information for the Doctor (symptoms, dangers, treatment)
Symptomatic therapy if necessary.
Martin GmbH
D-82234 Wessling / Germany
Geschäftsführer / General Manager
Dr. Georg Baumann
Dipl.-Ing. Gunter Kürbis
Amtsgericht München
HRB 87040
Ust.-Id.-Nr. DE 128 235 758
WEEE-Nr. DE 22908382
VR-Bank Sta-Hg-Lbg
BLZ 700 932 00
Konto 655 67 87
BIC GEN0DEF1STH
IBAN DE 15700932000006556787
Fon +49 [0] 8153 9329-30
Fax +49 [0] 8153 9329-39
[email protected]
www.martin-smt.de
Tradename:
Article No:
Issue:
HT00.0061
January 2010
Page 2 of 6
_____________________________________________________________________________________________________
5. Fire Fighting Measures
5.1
Appropriate Extinguishing Media
Sprinkled water, foam, carbon dioxide, sand.
5.2
Extinguishing Media Unsuitable for Safety Reasons
Strong water jet.
5.3
Extraordinary Danger by Combustion Products
None
5.4
Special Protecting Equipment
Not necessary.
6. Accidental Release Measures
6.1
Personal Precautions
None.
6.2
Environmental Precautions
Do not pour it into the drainage.
6.3
Methods of Cleaning / Absorption
Absorb with sand, sawdust or similar.
7. Handling and Storage
7.1
Handling
7.1.1 Instructions for secure working
Do not eat, drink or smoke during work. Do not inhale aerosols.
Spray: use it only in ventilated rooms.
7.2
Storage
Only in the original container, store at room temperature and normal humidity.
Spray: according to the national instructions (Germany: TRG 300).
7.3
Specifications for stockholding and containers
-
7.4
Storage with other products
Do not store together with strong oxidizing agents.
8. Exposure Controls and Personal Protective Equipment
8.1
Exposure Limit Values
310 mg/m³ on the basis of the C-4/C-5-alcohols
1.800 mg/m³ Propane; 2.400 mg/m³ Butane
8.2
Exposure Controls
Ventilate exposed areas. The exposition limit will not be reached when the complete content of a 200 ml can is sprayed
in a room of 20 m².
Martin GmbH
Dr. Georg Baumann
HRB 87040
Ust.-Id.-Nr. DE 128 235 758
VR-Bank Sta-Hg-Lbg
BLZ 700 932 00
Konto 655 67 87
BIC GEN0DEF1STH
IBAN DE 15700932000006556787
Fon +49 [0] 8153 9329-30
Fax +49 [0] 8153 9329-39
[email protected]
www.martin-smt.de
Tradename:
Article No:
Issue:
HT00.0061
January 2010
Page 3 of 6
_____________________________________________________________________________________________________
8.3
Occupational Exposure Controls
8.3.1 Respiratory Protection:
not necessary when used as directed
8.3.2 Hand Protection:
8.3.3 Eye Protection:
8.3.4 Skin Protection:
8.4
Limitation and Controlling of Immission
9. Physical and Chemical Properties
9.1
9.2
9.3
General Information
Aggregate state/form
Color
Odor
liquid / pressurized aerosol
bright yellowish
characteristic for the product
Security Relevant Datas
pH value: n.a.
Further Information
Description
DIN
Oil
Aerosol
Pourpoint
ISO 3016
-10°C
n.a.
Flashpoint
ISO 51758
52°C
n.a.
Vapor pressure 20°C
5 hP
Inner pressure 7.5 Bar
Density 20°C
0.865 g/cm³
0.775 g/cm³
Limits of Explosion
none
Refering to propellant Propan-Butan:
1.5 –10.9 Vol%
Solubility in water / 20°C
Emulsion
Emulsion
Distribution coefficient n-Octanol/water
n.a.
n.a.
Kinematic Viscosity / 20°C
ca. 58 mm²/s
n.a.
n.a. = not applicable
10. Stability and Reactivity
10.1
Conditions to Avoid
Oil:
Heating > 100°C,
Aerosol:
Heating > 50°C
10.2
Substances to Avoid
Strong oxidants which may cause self ignition at higher temperatures.
10.3
Hazardous Decomposition Products
No
Martin GmbH
Dr. Georg Baumann
HRB 87040
Ust.-Id.-Nr. DE 128 235 758
VR-Bank Sta-Hg-Lbg
BLZ 700 932 00
Konto 655 67 87
BIC GEN0DEF1STH
IBAN DE 15700932000006556787
Fon +49 [0] 8153 9329-30
Fax +49 [0] 8153 9329-39
[email protected]
www.martin-smt.de
Tradename:
Article No:
Issue:
HT00.0061
January 2010
Page 4 of 6
_____________________________________________________________________________________________________
11. Toxicological Information
11.1
Remarks
The toxicological data are based on the observation and experiments in the course of more than 90 years. Among others
many users apply it even on the skin, partially internal, too (Non-Spray). Observations on intoxications, chronical-toxical
action have not been reported.
11.2
Toxicological Investigations
Acute Toxicity:
Specific symptoms in animal experiment:
Irritant or discharge action:
Sensibilization:
Sub acute or chronic toxicity:
Carcinogenic, mutagenic or teratogenic hazards:
LD50 (rat, oral) > 10 000 mg/kg
(complete filling of the stomach)
no
slight irritation when in contact with the eye.
no sensibilization observed.
permanent contact with skin is not hazardous nor irritating.
the components showed no carcinogenic potential in
animal experiments.
12. Environmental Information
12.1
Eco toxicity
No data available.
12.2
Mobility
Emulsification in water, immobilized in soil.
12.3
Persistence, elimination and Degradability
The product is nearly completely biodegradable (Bartha-Pramer-Test).
12.4
Bioaccumulation
None (see 12.3).
12.5
Additional Ecological Data
No.
13. Disposal Considerations
13.1
13.2
Waste (Products)
Waste classification:
130202 Engine, turbine and gearing oils (see national instructions)
Uncleaned containers
Empty container completely.
Recommendations: the containers are recyclable
Recommended cleaning material: Warm water with tenside. Waste water biodegradable.
14. Transport Information
14.1
Transport Via Road/Railway
14.1.1 Oil
UN No:
Classification code:
including 5 litre:
more than 5 litre:
Martin GmbH
Dr. Georg Baumann
1268 Petroleum distillates, n.o.s. (alcohol)
3, F1, III, ADR
“limited quantity“ (max. up to 45 kg/box)
Dangerous Good
HRB 87040
Ust.-Id.-Nr. DE 128 235 758
VR-Bank Sta-Hg-Lbg
BLZ 700 932 00
Konto 655 67 87
BIC GEN0DEF1STH
IBAN DE 15700932000006556787
Fon +49 [0] 8153 9329-30
Fax +49 [0] 8153 9329-39
[email protected]
www.martin-smt.de
Tradename:
Article No:
Issue:
HT00.0061
January 2010
Page 5 of 6
_____________________________________________________________________________________________________
14.1.2 Aerosol
UN No:
1950 Aerosols, flammable
2,5F,ADR
50 ml is no Dangerous Good according to ADR
100 and 200 ml are „limited quantity“, (max. up to 30kg/box)
14.2
Transport Via Sea (IMDG-Code/GGVSea)
14.2.1 Oil
UN No:
Packaging Group:
EmS:
1268 Petroleum distillates, n.o.s. (alcohol)
3
III
F-E, S-E
including 5 l:
more than 5 l:
„limited quantity“ (max. up to 30 kg/box)
Dangerous Good
14.2.2 Aerosol
UN No:
Packaging Group:
EmS:
1950 Aerosols, flammable,
2
F-D, S-U
50 ml is no Dangerous Good according to IMDG Code
100 and 200 ml are „limited quantity“, (max. up to 30kg/box)
14.3
Transport Via Air (ICAO-IATA/DGR)
14.3.1 Oil
Indication:
UN No:
Packaging Group:
Packing Instructions:
Dangerous Good
1268 Petroleum distillates, n.o.s.,
3.3
III
309 (Passenger) / 310 (Cargo)
14.3.2 Aerosol
Indication:
UN No:
Packaging Group:
Packing Instructions:
Dangerous Good
1950 Aerosols, flammable,
2.1
203 (Passenger and Cargo)
15. Regulatory Information
15.1
Typification according to EU-Rules
Aerosol:
R12
Oil > 125ml: R 10
S 7, 16:
15.2
Highly inflammable, F+
Dispatch box: “UN 1950 Aerosole”
Inflammable
Keep container well closed. Do not smoke.
National Regulations
Aerosols: Caution! Highly inflammable. Contents under pressure. Do not expose to heat or store above 50°C. Do not
spray into flames, do not puncture nor incinerate containers. Keep out of reach of children.
15.2.1 Restrictions of employment: 15.2.2 Failure regulation act: 15.2.3 Classification combustible liquids regulation. Martin GmbH
Dr. Georg Baumann
HRB 87040
Ust.-Id.-Nr. DE 128 235 758
VR-Bank Sta-Hg-Lbg
BLZ 700 932 00
Konto 655 67 87
BIC GEN0DEF1STH
IBAN DE 15700932000006556787
Fon +49 [0] 8153 9329-30
Fax +49 [0] 8153 9329-39
[email protected]
www.martin-smt.de
Tradename:
Article No:
Issue:
HT00.0061
January 2010
Page 6 of 6
_____________________________________________________________________________________________________
15.2.4 Technical instruction air: 15.2.5 Water hazardous Classification: WGK 1
15.2.6 Other instructions, restrictions and prohibitions: 16. Other Information
16.1
Additional Information
The information contained herein is given to the best of our knowledge, however it does not exempt our customers from
an individual inspection of the specific requirements for the application of the product. The preceding information refers
especially to the safety requirements and is no warranty for the product itself. The technical data sheets are referred to.
The original version of this material safety data sheet is in German. The present English version is only a translation.
Regulatory requirements are subject to change and may differ from one nation to another. It is the buyers/users
responsibility to ensure that its activities comply with national, state or provincial, and local laws and regulations.
The copying or quotation of contents is prohibited, even in extracts.
Martin GmbH
Dr. Georg Baumann
HRB 87040
Ust.-Id.-Nr. DE 128 235 758
VR-Bank Sta-Hg-Lbg
BLZ 700 932 00
Konto 655 67 87
BIC GEN0DEF1STH
IBAN DE 15700932000006556787
Fon +49 [0] 8153 9329-30
Fax +49 [0] 8153 9329-39
[email protected]
www.martin-smt.de

Balistol - martin

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