Graphical Abstracts Syntheses and

Graphical Abstracts
Current Organic Synthesis, 2014, Vol. 11, No. 1
Graphical Abstracts
Current Organic Synthesis, 2014, Vol. 11, No. 1
3
Syntheses and Functionalizations of Porphyrin Macrocycles
Maria da G.H. Vicente* and Kevin M. Smith
*Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, U.S.A
Current Organic Synthesis, 2014, Vol. 11, No. 1
29
Synthesis and Functionalization of Corroles. An Insight on Their Nonlinear Optical Absorption
Properties
Carla I.M. Santos, Joana F.B. Barata, Mário J.F. Calvete, Luís S.H.P. Vale, Danilo Dini, Moreno Meneghetti, Maria
G.P.M.S. Neves, Maria A.F. Faustino, Augusto C. Tomé and José A.S. Cavaleiro
*Department of Chemistry, University of Rome “La Sapienza”, 00185 Rome, Italy and Department of Chemistry, University of Aveiro 3810-193 Aveiro, Portugal
Current Organic Synthesis, 2014, Vol. 11, No. 1
Chlorins: Natural Sources, Synthetic Developments and Main Applications
Kleber T. de Oliveira*, Patrícia B. Momo, Francisco F. de Assis, Marco A.B. Ferreira and Timothy J. Brocksom
*Departamento de Química, Universidade Federal de São Carlos, Rodovia Washington Luís, km 235 - SP-310, 13565-905, São Carlos - SP – Brazil
42
i
ii Current Organic Synthesis, 2014, Vol. 11, No. 1
Graphical Abstracts
Current Organic Synthesis, 2014, Vol. 11, No. 1
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Current Organic Synthesis, 2014, Vol. 11, No. 1
67
Glycosylated Metal Phthalocyanines
Michael Hanack*, Göran Crucius, Mário J.F. Calvete and Thomas Ziegler
*Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany
Metalloporphyrins Immobilized on Silica and Modified Silica as Catalysts in Heterogeneous
Processes
Shirley Nakagaki*, Gabriel K.B. Ferreira, Alex L. Marçal and Katia J. Ciuffi
*Universidade Federal do Paraná, Departamento de Química -Laboratório de Bioinorgânica e Catálise, CP 19081, CEP 81531-980, Curitiba, Paraná, Brazil
Current Organic Synthesis, 2014, Vol. 11, No. 1
Microwave-Assisted Synthesis and Reactivity of Porphyrins
Marta Pineiro*
*Departamento de Química, Universidade de Coimbra, Rua Larga 3004-535 Coimbra, Portugal
89
Graphical Abstracts
Current Organic Synthesis, 2014, Vol. 11, No. 1
Current Organic Synthesis, 2014, Vol. 11, No. 1
110
Porphyrins and Phthalocyanines Decorated with Dendrimers: Synthesis and Biomedical
Applications
Flávio Figueira, Patrícia M.R. Pereira, Sandrina Silva, José A.S. Cavaleiro and João P.C. Tomé*
*QOPNA, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal and Department of Organic Chemistry, Gent University, B-9000, Gent, Belgium
Current Organic Synthesis, 2014, Vol. 11, No. 1
127
Tetrapyrrolic Macrocycles: Potentialities in Medical Imaging Technologies
Mário J.F. Calvete*, Ana V.C. Simões, César A. Henriques, Sara M.A. Pinto and Mariette M. Pereira
*Centro de Química de Coimbra, Departamento de Química, Universidade de Coimbra, Rua Larga, 3004-535, Coimbra, Portugal
Medical Imaging Technologies
N
N
N
N
M
PET
N
N
N
M
N
N
N
FI
N
N
MRI
Current Organic Synthesis, 2014, Vol. 11, No. 1
141
Electrochemical Synthesis of Polyfunctionalized Indoles in Aqueous Medium from Catechols
and Ketene N,S-acetals
Xiao-Guang Gao, Ni-Tao Zhang, Cheng-Chu Zeng*, Yong-Dong Liu, Li-Ming Hu and Hong-Yu Tian
* College of Life Science & Bioengineering, Beijing University of Technology, Beijing 100124, China
OH
OH
O
1a
NHR1
R2
SCH3
R1
5a-5h
O
OH
N
H3CS
OH
O
Anode
O
R2
9a-9h
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iv Current Organic Synthesis, 2014, Vol. 11, No. 1
Graphical Abstracts
Current Organic Synthesis, 2014, Vol. 11, No. 1
149
Design of New N-polyether Pyrazole Derived Ligands: Synthesis, Characterization and
Regioselectivity
Miguel Guerrero, José A Pérez, Josep Ros, Vicenç Branchadell, Eva Pellicer, Jordi Sort and Josefina Pons*
* Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, 08193-Bellaterra-Cerdanyola, Barcelona, Spain
R1
R2
N
N
H
Cl(CH2CH2O)3CH3
R1= Py
R2=Ph
R1= Py
R2=Me
R1= Ph
R2=Me
L4
L1
N
N
N N
N N
O
O
O
O
O
O
+
L3
L4'
N N
N
O
O
O
N N
O
+
O
O
L3'
N N
O
O
O
Current Organic Synthesis, 2014, Vol. 11, No. 1
156
Selective Oxidation of Sulfides to Sulfoxides with Tert-Butylnitrite as an Alternative Oxidant
Bing Yu, Zhen-Feng Diao, An-Hua Liu, Xu Han, Bin Li, Liang-Nian He* and Xiang-Ming Liu
* State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China
Tert-butylnitrite proved to be an efficient oxidant for selective oxidation of sulfides to sulfoxides promoted by Fe(NO 3)3·9H2O under mild
conditions.
t-BuONO (3.0 equiv.)
R1
S
R2
O
R1
Fe(NO3)3 ˙ 9H2O (20 mol%)
CH3CN, 60
R1, R2 = aryl, alkyl
9 examples
oC,18
S
R2
- 24 h
High selectivity
Yield: moderate to excellent
Current Organic Synthesis, 2014, Vol. 11, No. 1
161
The Addition of Dialkyl Phosphites and Diphenylphosphine Oxide on the Triple Bond of
Dimethyl Acetylenedicarboxylate under Solvent-Free and Microwave Conditions
György Keglevich*, Erika Bálint, Judit Takács, László Drahos, Krzysztof Huben and Stefan Jankowski
* Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, 1521 Budapest, Hungary
Mono- and bisadducts were prepared by the MW-assisted addition of dialkyl phosphites or diphenylphosphine oxide to the triple bond of
dimethyl acetylenedicarboxylate.
COOMe
+
COOMe
Y2P(O)H
MW
T, t
no solvent
MeOOC
P(O)Y2
MeOOC
P(O)Y2
MeOOC
P(O)Y2
+
MeOOC
Y= MeO, EtO, BuO, BnO, Ph