amarela Descarte dos resíduos do composto: soluções

Transcrição

amarela Descarte dos resíduos do composto: soluções
FERRIC CITRATE, N-HYDRATE
Tarja: amarela
Descarte dos resíduos do composto: soluções aquosas: pia, após neutralização. Sólidos:
lixo
1. Product Identification
Molecular Weight: Not applicable.
Chemical Formula: C6H8O7.xFe
3. Hazards Identification
Emergency Overview
WARNING! TOXICOLOGICAL PROPERTIES UNKNOWN. HARMFUL IF
SWALLOWED. AFFECTS THE LIVER. MAY BE HARMFUL IF INHALED. MAY
CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT.
Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 0 - None
Contact Rating: 1 - Slight
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Potential Health Effects
Information on the human health effects from exposure to this substance is limited.
Inhalation::
No information found, but compound should be handled as a potential health hazard. May
cause irritation to the respiratory tract. Symptoms may include coughing, sore throat, labored
breathing, and chest pain.
Ingestion::
May cause irritation to the gastrointestinal tract. Symptoms may include nausea, vomiting and
diarrhea. Low systemic toxicity in small quantities but larger doses may cause systemic
effects. Pink urine discoloration is a strong indicator of iron poisoning. Liver damage, coma
and death may follow, sometimes delayed as long as three days.
Skin Contact:
No information found, but compound should be handled as a potential health hazard. May
cause irritation with redness and pain.
Eye Contact:
No information found, but compound should be handled as a potential health hazard. May
cause irritation, redness and pain.
Chronic Exposure:
Repeated Ingestion: may cause liver damage.
Aggravation of Pre-existing Conditions:
No information found.
4. First Aid Measures
Inhalation::
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Ingestion::
Give large amounts of water to drink. Never give anything by mouth to an unconscious
person. Get medical attention.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated
Clothing and shoes. Get medical attention. Wash Clothing before reuse. Thoroughly clean
shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper
eyelids occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Fire:
Not expected to be a fire hazard.
Explosion:
No information found.
Fire Extinguishing Media:
Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective Clothing and NIOSH-approved self-contained
breathing apparatus with full facepiece operated in the pressure demand or other positive
pressure mode.
6. Accidental Release Measures
Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of
spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up
and place in a suitable container for reclamation or disposal, using a method that does not
generate dust.
7. Handling: and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against
physical damage. Containers of this material may be hazardous when empty since they retain
product residues (dust, solids); observe all warnings and precautions listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
-ACGIH Threshold Limit Value (TLV):
1 mg/m3 (TWA) soluble iron salt as Fe
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below
the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can
control the emissions of the contaminant at its source, preventing dispersion of it into the
general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of
Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten
times the exposure limit or the maximum use concentration specified by the appropriate
regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist
respirator may be worn up to 50 times the exposure limit, or the maximum use concentration
specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a full-facepiece
positive-pressure, air-supplied respirator. WARNING: Air-purifying Respirators do not
protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective Clothing, including boots, gloves, lab coat, apron or coveralls, as
appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is
possible. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance: Dark red to brown powder. Odor: Odorless.
Solubility: Complete (100%)
% Volatiles by volume @ 21C (70F): 0
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and Storage.
Hazardous Decomposition Products:
Carbon dioxide and carbon monoxide may form when heated to decomposition. May produce
toxic iron oxide fumes when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Strong oxidizers.
Conditions to Avoid:
Incompatibles.
11. Toxicological Information
No LD50/LC50 information found relating to normal routes of occupational exposure.

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