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jomix b sp 136/10 jomix b sp 136/10
Page : 1 SAFETY DATA SHEET Revised edition no : 0 - 1 Date : 16 / 8 / 2010 Supersedes : 0 / 0 / 0 JOMIX B SP 136/10 JOMIX B SP 136/10 C : Corrosive 8 : Corrosive substance. 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Identification of the product : Liquid. Trade name : JOMIX B SP 136/10 Type of product : Extinguishing product Use : Fire extinguishing agent Emergency phone no : TEL : +32 65 32 15 38 2 HAZARDS IDENTIFICATION Risk Phrases : Corrosive to eyes, respiratory system and skin. Dangerous product : This product is flammable. In use, may form flammable/explosive vapour-air mixture. Primary route of exposure : Inhalation. Eyes contact. Skin contact. Symptoms relating to use - Inhalation : Breathing difficulties. Cough. Sore throat. - Skin contact : Redness, pain. Causes burns. - Eye contact : Redness, pain. Blurred vision. Tears. Risk of serious damage to eyes. - Ingestion : Burning sensation. Cough. Cramps. May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Swallowing a small quantity of this material will result in serious health hazard. Must not come into contact with food or be consumed. 3 COMPOSITION/INFORMATION ON INGREDIENTS Components : This product is hazardous. Substance name 2-(2-butoxyethoxy)ethanol : Ethanol : Perfluorinated amphoteric surfactant : alkyl polyglucoside : Urea : Contents Between 5 and 15 % Between 5 and 10 % Between 5 and 15 % Between 2 and 20 % Between 1 and 10 % CAS No 112-34-5 64-17-5 --------57-13-6 EC No 203-961-6 200-578-6 --------200-315-5 Annex No 603-096-00-8 603-002-00-5 ------------- Ref --------------------- REACH Classification Xi; R36 F; R11 Xn; R65 C; R35 Xi; R36/37/38 4 FIRST AID MEASURES First aid measures - Inhalation : Assure fresh air breathing. If not breathing, give artificial respiration, preferably mouth to mouth. Seek medical attention immediately. - Skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Seek medical advice. Rinse immediately with plenty of water. - Eye contact : Contact ophthalmologist immediately. Continue to rinse eye with clean water for 20-30 minutes, retracting eyelids often. - Ingestion : Rinse mouth. Do not induce vomiting because of corrosive effects. Take to hospital. 5 FIRE-FIGHTING MEASURES Flammable class : This product is flammable. Specific hazards : May form flammable/explosive vapour-air mixture. Hazardous combustion products : Thermal decomposition generates : Corrosive vapours. Prevention : No naked lights. No smoking. Extinguishing media : Powder. Sand. Carbon dioxide (CO2). Water. Surrounding fires : Use water spray or fog for cooling exposed containers. Protection against fire : Do not enter fire area without proper protective equipment, including respiratory protection. Special procedures : Exercise caution when fighting any chemical fire. Feuerschutz JOCKEL GmbH & Co. KG HRA 21611 AG Wuppertal, vertreten durch Jockel Verwaltungs- GmbH, HRB 19010 AG Wuppertal, diese vertreten durch die Geschäftsführer Klaus-Gerhard Jockel, Frank Jockel, Holger Jockel. UST.Id.Nr. DE 814 331 297 – ST-Nr. 126/5835/0225 – Es gelten unsere allgemeinen Geschäftsbedingungen. Page : 2 SAFETY DATA SHEET Revised edition no : 0 - 1 Date : 16 / 8 / 2010 Supersedes : 0 / 0 / 0 JOMIX B SP 136/10 JOMIX B SP 136/10 6 ACCIDENTAL RELEASE MEASURES Personal precautions : Spill should be handled by trained cleaning personnel properly equipped with respiratory and eye protection. General precautions : Remove ignition sources. Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters. Clean up methods : Collect spills and put it into appropriated container. 7 HANDLING AND STORAGE General : No naked lights. No smoking. Store and handle as though always a serious potential fire/explosion and health hazard exists. Precautions in handling and storage : In use, may form flammable vapour-air mixture. Personal protection : Avoid all unnecessary exposure. Ensure prompt removal from eyes, skin and clothing. Technical protective measures : Proper grounding procedures to avoid static electricity should be followed. Both local exhaust and general room ventilation are usually required. Proper grounding procedures to avoid static electricity should be followed. Storage : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place. Keep container closed when not in use. Do not store in corrodable metal. Storage - away from : Heat sources. Direct sunlight. Heat sources. Handling : Keep away from food, drink and animal feeding stuffs. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Handle empty containers with care because residual vapours are flammable. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protection - Respiratory protection : Approved dust or mist respirator should be used if airborne particles are generated when handling this material. - Hand protection : Wear suitable gloves resistant to chemical penetration. - Skin protection : Wear suitable protective clothing. - Eye protection : Chemical goggles or face shield with safety glasses. - Ingestion : When using, do not eat, drink or smoke. Industrial hygiene : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Provide local exhaust or general room ventilation. Occupational Exposure Limits : Ethanol : TLV© -TWA [ppm] : 1000 Ethanol : OEL (UK)-LTEL [ppm] : 1000 Ethanol : LTEL - UK [mg/m³] : 1920 Ethanol : LTEL - UK [ppm] : 1000 Ethanol : VLE - France [mg/m³] : 9500 Ethanol : VLE - France [ppm] : 5000 Ethanol : VME - France [mg/m³] : 1900 Ethanol : VME - France [ppm] : 1000 Ethanol : Arbeitsplatzgrenzwert AGW - Germany [mg/m³] TRGS 900 : 960 Ethanol : MAK - Germany [ppm] : 500 Ethanol : Spitzenbegrenzung / Überschreitungsfaktor AGW - Germany TRGS 900 : 2 Ethanol : MAK (AU) Tagesmittelwert (ml/m³) : 1000 Ethanol : MAK (AU) Tagesmittelwert (mg/m³) : 1900 Ethanol : MAK (AU) Kurzzeitwerte (ml/m³) : 2000 Ethanol : MAK (AU) Kurzzeitwerte (mg/m³) : 3800 Ethanol : VLA-ED [ppm] : 1000 Ethanol : VLA-ED [mg/m³] : 1910 Ethanol : NGV - [ppm] : 500 Ethanol : NGV - [mg/m³] : 1000 Ethanol : KTV - [ppm] : 1000 Ethanol : KTV - [mg/m³] : 1900 Feuerschutz JOCKEL GmbH & Co. KG HRA 21611 AG Wuppertal, vertreten durch Jockel Verwaltungs- GmbH, HRB 19010 AG Wuppertal, diese vertreten durch die Geschäftsführer Klaus-Gerhard Jockel, Frank Jockel, Holger Jockel. UST.Id.Nr. DE 814 331 297 – ST-Nr. 126/5835/0225 – Es gelten unsere allgemeinen Geschäftsbedingungen. Page : 3 SAFETY DATA SHEET Revised edition no : 0 - 1 Date : 16 / 8 / 2010 Supersedes : 0 / 0 / 0 JOMIX B SP 136/10 JOMIX B SP 136/10 8 EXPOSURE CONTROLS/PERSONAL PROTECTION (Continue) Ethanol : Grænserværdier (DK) (ppm) : 1000 Ethanol : HTP-värden - 8 H - [ppm] : 1000 Ethanol : HTP-värden - 8 H - [mg/m³] : 1900 Ethanol : HTP-värden - 15min - [ppm] : 1300 Ethanol : Grænserværdier (DK) : 1900 Ethanol : HTP-värden - 15min - [mg/m³] : 2500 Ethanol : GV Value Limit (Norway) [ppm] : 500 Ethanol : GV Value Limit (Norway) [mg/m³] : 950 Ethanol : 8-Hour TWA (PL) (NDS) (mg/m³) : 1900 Ethanol : TLV-TWA (Belgium) (ppm) : 1000 Urea : TLV - ACGIH [mg/m³] : 10 Urea : OSHA PEL [mg/m³] : 15 9 PHYSICAL AND CHEMICAL PROPERTIES Physical state at 20 °C : Liquid. Colour : Yellow-brown. Odour : Characteristic. pH value : 8.5 Density : 1.09 Refraction index (°) : 1.39-1.40 Viscosity Solubility in water : Complete. Flash point [°C] : 48.5 10 STABILITY AND REACTIVITY Stability and reactivity : Stable under normal conditions. Hazardous decomposition products : Thermal decomposition generates : Corrosive vapours. May release flammable gases. Hazardous reactions : Strong oxidizing agents. Hazardous properties : May form flammable/explosive vapour-air mixture. Materials to avoid : Strong oxidizers. Conditions to avoid : Open flame. Direct sunlight. Overheating. 11 TOXICOLOGICAL INFORMATION Toxicity information : Corrosive to eyes, respiratory system and skin. 12 ECOLOGICAL INFORMATION Ecological effects information : No data available. 13 DISPOSAL CONSIDERATIONS General : Hazardous waste. Dispose in a safe manner in accordance with local/national regulations. Feuerschutz JOCKEL GmbH & Co. KG HRA 21611 AG Wuppertal, vertreten durch Jockel Verwaltungs- GmbH, HRB 19010 AG Wuppertal, diese vertreten durch die Geschäftsführer Klaus-Gerhard Jockel, Frank Jockel, Holger Jockel. UST.Id.Nr. DE 814 331 297 – ST-Nr. 126/5835/0225 – Es gelten unsere allgemeinen Geschäftsbedingungen. Page : 4 SAFETY DATA SHEET Revised edition no : 0 - 1 Date : 16 / 8 / 2010 Supersedes : 0 / 0 / 0 JOMIX B SP 136/10 JOMIX B SP 136/10 14 TRANSPORT INFORMATION General information UN No. : 3267 Labelling ADR :8 Land transport H.I. nr : 80 Proper shipping name : UN3267 LIQUIDE ORGANIQUE CORROSIF, BASIQUE, N.S.A. (alkyl polyglucoside), 8, II, (E) - ADR Class : 8 - ADR Packing group : II Sea transport - IMO-IMDG code : Class : 8 - IMO Packing group : II - IMDG-Marine pollution : YES - Emergency Schedule (EmS) - Fire : F-A S-B Air transport - ICAO/IATA : Packaging instructions cargo : 812 Packaging instructions passenger: 808 - Proper shipping name : CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. • Class : 8 - IATA Packing group : II 15 REGULATORY INFORMATION Symbol(s) : C : Corrosive R Phrase(s) : R10 : Flammable. R34 : Causes burns. S Phrase(s) : S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection. S45 : In case of accident or if you feel unwell, seek medical advice immediately (show the label when possible). 16 OTHER INFORMATION List of relevant R phrases (heading 3) : R11 : Highly flammable. R35 : Causes severe burns. R36 : Irritating to eyes. R36/37/38 : Irritating to eyes, respiratory system and skin. R65 : Harmful : may cause lung damage if swallowed. Further information : None. The contents and format of this SDS are in accordance with REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document Feuerschutz JOCKEL GmbH & Co. KG HRA 21611 AG Wuppertal, vertreten durch Jockel Verwaltungs- GmbH, HRB 19010 AG Wuppertal, diese vertreten durch die Geschäftsführer Klaus-Gerhard Jockel, Frank Jockel, Holger Jockel. UST.Id.Nr. DE 814 331 297 – ST-Nr. 126/5835/0225 – Es gelten unsere allgemeinen Geschäftsbedingungen.
