2nd MEDITERRANEAN CLAY MEETING, AVEIRO, 1998

Proceedings of the
2nd MEDITERRANEAN CLAY MEETING, AVEIRO, 1998
INDEX
INVITED LECTURES (Volume 1)
Isotopic constraints to the illitization process in progressively buried diagenetic
volcano-sedimentay rocks
NORBERT CLAUER
1-7
Longevity of clay barriers in waste disposal
SANTIAGO LEGUEY
8-33
Characteristics, uses and behaviour of the illitic-chloritic clays for ceramics production
BRUNO FABBRI
34-46
Kinetic aspects of clay minerals formation
JOSÉ LINARES & J.F. HUERTAS
47-65
Archaeometry of roman ceramics from Suasa (Italy): evidences of local and foreign
production
N. MORANDI, M. NANNETTI & C. TAMPELLINI
66-77
Do marine clays record paleoclimates?
MÉDARD THIRY
78-98
Adsorption of organic cationic dyes by smectite minerals
SHMUEL YARIV
99-127
Statistical analysis of mineralogical parameters used as lithostratigraphic and
environmental markers
FERNANDO ROCHA
128-152
EXTENDED ABSTRACTS (Volume 2)
Chlorite, corrensite and micas in fluvio-lacustrine mudrocks of the Cameros
basin (NE Spain)
J. F. BARRENECHEA, M. RODAS, J. ALONZO-AZCÁRATE, M. FREY & J. R. MAS
1-5
Diagenesis and low-grade metamorphism in tithonian-berrasian sediments from the
Cameros basin (NE Spain): clay mineral assemblages and crystallinity data
J. F. BARRENECHEA, M. RODAS M. FREY & J. R. MAS
6-10
Characterization of the “stevensite precursor” from the Tagus basin (Spain)
C. de Santiago Buey, M. Suárez Barrios, E. Romero & M. Doval Montoya
11-16
Illite and chlorite “crystallinity” in diagenetic to low-grade metamorphic
rocks from the Maláguide Complex (Betic Cordillera, Spain)
M. D. RUIZ CRUZ & P. RODRÍGUEZ JIMÉNEZ
17-21
i
Post-magmatic clay minerals in a basaltic volcanic neck from Portugal
(Lisbon Volcanic Complex)
JOSÉ BRILHA, M. SEQUEIRA BRAGA, D. PROUST & P. DUDOIGNON
22-27
Metamorphic vermiculite or hydrated biotite: a XRD, DTA/TG and TEM/AEM study
M. D. RUIZ CRUZ
28-33
Characterization of a saponite modified by acid and pillaring treatment
M. SUÁREZ, C. DE SANTIAGO, E. ROMERO, R. TORANZO & J. M. MARTÍN POZAS
34-39
The genesis of authigenic illite: some considerations on SEM and TEM observations
of natural samples
M. ARDUINI, A. ORTENZI, A. LOPES GALINDO, M. SETTI, A. YEBRA & A. DI GIULIO
40-45
Micas transformation in a soil developped on a gneiss: an XRD, HRTEM and AEM study
M. AMOURIC, B. ALESSANDRIA, D. AQUILANO & O. GRAUBY
46-47
The problem of serpentine curvature: influence of cation size and elastic theory
R. PERBOST, M. AMOURIC, J. OLIVES, O. GRAUBY & F. MARTIN
48-49
Mineralogical tools to distinguish different sediments types in a foredeep basin
(Mt. Cervarola Sandstones Formations, Early Miocene, Northern Italy)
F. TA TEO, M. A NDREOZZ I & E. DINELL I
50-55
Geochemistry of two peats suitable for medical uses and their behaviour during
water leaching and cation exchange
V.SUMM A & F. TA TEO
56-59
Chemical and oxygen isotope compositions of clay minerals in the playa-lake deposit
system from calatayud basin, Northeastern Spain
M. J MA Y A YO , B. BA ULUZ & J. M. GONZÁ LEZ LÓ PEZ
60-64
Study of some Tertiary Tunisian palygorskitic outcrops
A. BEN ABOUD, F. JAMOUSSI, M. SETTI, A. LÓPEZ-GALINDO, P. FENOLL, M. BEDIR
& S. AB DELJAOUED
65-70
Study of cadmium adsorption in sepiolite: influence on the dehydratation process
A . Y EBRA , C. VISERAS , C. FERRA GINA , J. D. MAR TÍN-RAM OS & A . LÓPEZ-GA LINDO
71-76
Ionic exchange process between bentonite interlayer cations and granitic solutions
F. .JAVIER HUERTAS , C. DE JIMÉNEZ CISNER OS, E. CABA LL ERO, F. HUERTAS & J. LINARE S
77-82
Formation of phyllosilicates 2:1 by hydrothermal alteration of volcanic glass
S. DE LA FUENTE LÓPEZ, J. CUA DROS OJEDA & J. LINARE S
83-86
Zeolite and smectite crystallization on a bentonite matrix in an hydrothermal
alkaline environment
S. RA MÍREZ, R. VIGIL DE LA VILL A , J. CUEVA S & S. LEGUEY
87-92
Seasonal influence of cyclonic gyres on dispersion of clay minerals in the
northern and central adriatic
LUCIA NO TOM A DIN, MIRKO SC A TA SS A & VLA DIMIRO LA NDUZZ I
93-95
Diagenesis of trioctahedral clays in a sedimentary-magmatic sequence in the Jordan valley
(Dead-sea rift), Israel
A. SA NDLER, Y . NA THA N, Y . ESHET & M. RAA B
96-101
ii
Clay mineralogy of albian sediments in a type section (san felices) from the southern border
of the basque-cantabrian basin (Northern Spain)
M. C. ZULUAGA, M. J. IRABIEN, F. J. SANGÜESA, A. ARANBURU, L. M. AGIRREZABALA
& J. AR OSTEGUI
102-107
Mineralogy of clays in calcisols of semiarid mountainous regions of SE Spain
Á NGEL FA Z CA NO, JOA QUÍN HERNÁ NDEZ BA STIDA & ROQUE ORTIZ SILL A
108-112
Mineralogical composition and genesis of the clay fraction of the paleosols found in
Carrascoy (Murcia, SE Spain)
ROQUE ORTIZ SILL A & Á NGEL FA Z CA NO
113-118
Mineralogy and genesis of clay of soils developed on volcanic rocks in the Southeast of Spain
M. J. DELGA DO INIESTA , M. T. FERNÁ NDEZ TA PIA & R.ORTIZ SILL A
119-123
Diagenetic-metamorphic evolution of South Portuguese Zone (SW Portugal)
I. ABA D, P. MA TA , F. NIETO & N. VELILL A
124-130
The smectite source in the argillaceous marine sediments deposited near
the SE-margin of the Tethys, Israel area - theoretical aspects
S. SHOVA L
131135
Geochemical differences between global rocks and clay fractions in Precambrian
and Paleozoic shales from Iberian range (NE Spain)
P. BA ULUZ , M. J. MA Y A YO , C.F. NIETO & J. M. G. LOPEZ
136-139
Iron oxides in clay fraction from soils in Southwest of Spain (Huelva)
P. R. RUBIO, C. MA QUEDA , J. L. P. RODRIGUEZ & A . VA LERO
140-144
Identification of paleosoil occurrences in Paludine MG-clay deposits. Genetic constrains
and evolution of authigenic clays. (Neogene Madrid basin, Spain)
M. POZO, J. CA SA S & J. L. M. VIDA LES
145-149
Mineralogical and organic parameters used as lithostratigraphical markers in sequences of
Pomarão Anticline (Northeast sector of the South Portuguese Zone)
J. P. FERNA NDES, F. ROCHA, C. GOMES, & M. J. LEMOS DE SOUSA
150-154
Mineralogical and organic parameters used as lithostratigraphical markers in sequences of the
southwest sector of the South Portuguese Zone (Portugal)
L. P. MOÇO, F. ROCHA , C. GOMES & M. J. LEMOS DE SOUSA
155-159
Geodynamic evolution of the Aveiro region (Portugal) during Cretaceous, basedon clay mineralogy
F. ROCHA & C. GOMES
160-167
Clay minerals and isotopic data from the Miocene of the lower Tagus basin
(southern limb of Albufeira syncline, Setúbal Península, Portugal)
A . P. SILVA , F. ROCHA , P. LEGOINHA , J. PA IS, C. GOMES & M. TELLES A NTUNES
168-172
Bottom sediments of the northern Portuguese continental shelf: patterns of clay
minerals distribution
A. OLIVEIRA, F. ROCHA, J. A LVEIRINHO DIA S & C. GOMES
173-179
Contribution of clay mineralogy and geochemistry for the characterization of the
Kimmeridgian series of Quercy (NE Aquitaine Basin, France)
P. CAE TA NO, F. ROCHA, J. RE Y , C. GOMES & P. HA NTZ PERGUE
180-185
iii
Geology and technological properties of bentonite from Porto Santo Island
(Madeira Archipelago, Portugal)
J. ANTUNES, C. GALHANO, N. MARTINS, J. NAUDIN, J. SILVA, F. ROCHA, F. ALMEIDA
& C. GOMES
186-190
Surface acid/base properties of clays as determined by zetametry in organic medium
BER NAR D SIFFERT
191-197
Colloidal properties of concentrated lateritic suspensions
A. CERPA, M. T. GARCÍA-GONZÁLEZ, P. TARTAJ, J. REQUENA, L. GARCELL & C. J. SERNA
198
Composition and ceramic properties of raw materials for tile and bricks industry.
A case history of Pliocene-Pleistocene lacustrine clays from Tuscany and Liguria (Italy)
M. DONDI, M. MAR SIGLI, N. MORA NDI & C. P. BAR NAB È
199-203
Technological requirements of raw materials for heavy clay products
M. DONDI, M. MA RSIGLI & I. VENTURI
204-207
Use of spray-dried clays in water filtration
M. J. RIBEIRO, G. E. MÁR QUEZ & J. A . LABR INCHA
208-213
Inertization of metallurgical sludges in clay-based ceramics
D. M. COUTO, R. F. SILVA , F. CA STRO & J. A . ABR
L INCHA
214-219
Adsorption and interactions of methyl green to montmorillonite and sepiolite
G. RYT WO, S. NIR, M. CRESPIN & L. MA RGULIES
220-225
Inverse gas chromatography applied to clay minerals
E. PA PIRER & H. BA LAR D
226-230
Comparative study of the rheological properties of two kaolins, one residual the other
sedimentary, occuring nearby
MA NUEL CARA MÉS, IULIUS BOBOS & CELSO GOMES
231-237
Alteration of muscovite to kaolinite and from this to halloysite-7Å
IULIU BOBOS, JOELL E DUPLA Y & CELSO GOMES
238-243
Acid activation of portuguese palygorskites and/or esmectites
I. DIAS , M. SUARE Z, J. M. MAR TÍN-POZA S & S. PRA TES
244-248
Effect of the water on the Infra Red Spectra of the kaolinite-potassium acetate complex
FRA NCISC O FRA NCO, JA CINTA GONZÁ LEZ-JESÚS & MAR IA RUIZ CRUZ
249-254
Factors influencing the quantification of kaolin polymorphs by IR spectroscopy
FRA NCISC O FRA NCO, JA CINTA GONZÁ LEZ-JESÚS & MAR IA RUIZ CRUZ
255-259
Ecological synthesis and uses of 2,4-D esters herbicides employing clays and
related supports
B. CA SA L, L. LA MÍ, L. CUA DRA, J. MERINO, A. A LVARE Z & E. RUIZ-HITZ KY
260-262
Hydrotalcites and organo-hydrotalcites as sorbents to remove pesticides from water
M. V. VILL A , M. J. SÁ NCHEZ-MAR TÍN & M. SÁ NCHEZ-CA MA ZA NO
263-268
Glyphosate-hydrotalcites interaction as influenced by pH of the system
M. J. SÁ NCHEZ-MAR TÍN, M. V. VILL A & M. SÁ NCHEZ-CA MA ZA NO
269-274
iv
Proceedings of the
Experimental synthesis of smectite: an energetically favored octahedral sheet in
dioctahedral smectites
JAVIER CUA DROS, F. JAVIER HUERTAS , FRANCISC O HUERTAS & JOSÉ LINARE S
275-278
Smectite-herbicide association to reduce herbicide leaching
L. COX , R. CELIS, M. C. HERMOSIN & J. CORNEJO
279-284
Soil remediation and protection by organoclays
M. J. CARRI ZOSA , M. J. CA LDERON, M. C. HERM OSIN & J. CORNEJO
285-290
Organoclays for controlled release of an ureic herbicide
M. J. CA LDERON, M. C. HERMOSÍN , J. P. A GUER & J. CORNEJO
291-297
Physical, mineralogical and textural features of ceramic clays from Granada
province (Spain)
G. CULT RONE, E. SEBA STIÁ N PAR DO, O. CA ZA LL A VÁ
ZQUEZ & M. J. DE LA TORRE LÓPEZ
298-303
Firing of ceramic clays in industry and in laboratory: a comparative study for
controlling F, Cl and S emissions
B. FABBRI, G. ERCOLANI, E. GALAN, I. GONZALEZ, M. FORTEZA, A. MIRAS, M. I. CARRETERO
& P. A PAR ICIO
304-310
Hydrotalcite organic anion adsorption: effects of interlayer anion and layer composition
C. BARRI GA , M. GA ITÁN , M. C. HERM OSIN , I. PA VLOVIC
& M. A. ULIBARR I
311-316
The effect of CaCO3 content in moisture expansion of structural ceramics materials
C. SA NCHEZ, J. PARRA S, P. BARBA, J. VELA SCO & J. CERDEÑO
317-321
Technological behaviour of illitic-chloritic clays during the ceramic production process
M. I. CARRE TERO, M. DONDI, B. FABBRI , G. GUARINI , M. RAIM ONDO & I. VENTURI
322-327
Use of emanation thermal analysis (ETA) for in-situ characterisation of microstructure
changes of layer silicates and precursors of mullite ceramics. (i) basis of the technique
and application to kaolinite
J. PASCUAL COSP, P. J. SÁNCHEZ-SOTO, J. L. PÉREZ-RODRÍGUEZ, V. BÁLEK,
E. KLOSOVA & J. SUBR T
328-331
Use of emanation thermal analysis (ETA) for in-situ characterisation of microstructure
changes of layer silicates and precursors of mullite ceramics. (ii) study of mullite ceramic
precursors prepared from ground kaolinite and precipitated aluminium oxyde-hydroxide
J. PASCUAL COSP, P. J. SÁNCHEZ-SOTO, J. L. PÉREZ-RODRÍGUEZ, V. BÁLEK,
E. KLOSOVA & J. SUBR T
332-336
Application of FT-Raman spectroscopy to study of firing process in ceramic materials
J. M. A LIA , C. J. SÁ NCHEZ, J. PARRA S, H. G. M. EDWAR DS & F. J. G. NA VARR O
337-340
Clays typological classification- A contribution to the knowledge of Monsarro’s ore
deposit (Anadia)
C. CA RVA LHO & J. GRA DE
341-347
Abrasiveness of phyllosilicate fillers being conditioned by their physical and mineralogical
properties
J. VELHO & C. GOMES
348-353
Relationship between kaolin intrinsec characteristics when used as filler in paper and
the structural properties of paper
J. VELHO & C. GOMES
354-359
v
Rheological characterisation of ceramic suspensions with commercial dispersants
G. TA RÌ, J. M. F. FERR EIRA & A. T. FONSECA
360-365
A comparative study of thin clay films using glancing incidence diffraction geometry
and conventional Bragg-Brentano geometry
A. FERRE IRA, I. BOBOS, E. FERRA Z, C. SEQUEIRA & C. GOMES
366-369
Contribution of fluid inclusions analysis to elucidate the effect of hydrothermal alteration
in S. Vicente de Pereira Kaolin deposit (Portugal)
A . MIRA NDA , J. VELHO & C. GOMES
370-374
Characterization and ceramic properties of Bustos clay (Aveiro – Portugal)
J. COROA DO, J. MAR QUES, F. ROCHA & C. GOMES
375-380
Technological caracterisation of ceramic raw materials from the Itarare sub-group
(Parana Basin, Brazil)
R. FLORÊNCIO & J. MAR QUES
381-388
The reuse of papermaking sludge in ceramic industry
J. F. COROA DO, A. O. A MA DO & J. C. MAR QUES
389-394
Study of Tunisian bentonite properties for drilling fluids
M. BENNA , N. KBIR-ARI GUIB, M. A Y EDI, A , MA GNIN & F. BER GA Y A
vi
395-400