Publications

Publications Heinz GORNITZKA
218
Synthesis, structures, and antimalarial activities of some silver(I), gold(I) and
gold(III) complexes involving N-heterocyclic carbene ligands
C. Hemmert, A. Fabié, A. Fabre, F. Benoit-Vical, H. Gornitzka
Eur. J. Med. Chem., dx.doi.org/10.1016/j.ejmech.2012.11.038 (2012)
217
New silyl-substituted phosphaalkenes Mes*P=C(Cl)-Si(Cl)PhR, promising
building blocks in silicon and phosphorus chemistry
A. Bartok, R. Septelean, P. M. Petrar, G. Nemes, L.Silaghi-Dumitrescu, H.
Ranaivonjatovo, S.Mallet-Ladeira, N. Saffon, C. Hemmert, H. Gornitzka
J. Organomet. Chem., 724, 200-205 (2012)
216
Amide-functionalized Bis(NHC) systems: anion effect on gold–gold interactions
C. Hemmert, R. Poteau, F. Jean-Baptiste dit Dominique, P. Ceroni, G. Bergamini,
H. Gornitzka,
Eur. J. Inorg. Chem., 24, 3892-3898 (2012)
215
Organogermanium polymers prepared from s-indacene and carbodiimide
compounds
M. Dahrouch, E. Diaz, N. Gatica, Y. Moreno, I. Chavez, J. M. Manriquez, P.
Rivière, M. Rivière-Baudet, H. Gornitzka, A. Castel
Appl. Organometal. Chem., 26, 410–416 (2012)
214
Surprising unreactivity of cholesterol-5,6-epoxides towards nucleophiles
M. R. Paillasse, N. Saffon, H. Gornitzka, S. Silvente-Poirot, M. Poirot, P. De
Medina
J. Lipid Res., 53, 718-725 (2012)
213
Dimeric Gold Bis(carbene) Complexes by Transmetalation in Water
J. Cure, R. Poteau, I. C. Gerber, H. Gornitzka, C. Hemmert
Organometallics, 31, 619−626 (2012)
212
Combined Cation–π and Anion–π Interactions for Zwitterion Recognition
O. PERRAUD, V. ROBERT, H. GORNITZKA, A. MARTINEZ, J.-P. DUTASTA
Angew. Chem. Int. Ed., 51, 504-508 (2012)
211
Electronic Properties and Reactivity of an Isolable Phosphagermaheterocyclic
Carbene
D. GHEREG, S. LADEIRA, N. SAFFON, J. ESCUDIÉ, H. GORNITZKA
Angew. Chem. Int. Ed., 50, 7607-7610 (2011)
210
Versatile Stereoselective Cycloadditions between Heterocumulenes and
Phosphagermaallene Tip(tBu)Ge=C=PMes*: Experimental and Theoretical
Investigations
D. GHEREG, E. ANDRÉ, H. GORNITZKA, J. ESCUDIÉ, F. OUHSAINE, N. SAFFON, K.
MIQUEU, J.-M. SOTIROPOULOS
Chem. Eur. J., 17, 12763–12772 (2011)
209
Reactivity of Quinones with Phosphagermaallene Tip(tBu)Ge=C=PMes* Leading
to Four- and Six-Membered Heterocycles with an Exocyclic P=C Double Bond
D. GHEREG, H. GORNITZKA, J. ESCUDIÉ
Eur. J. Inorg. Chem., 281–288 (2011)
208
Synthesis, Structure and Electrochemistry of Macrocyclic Tetrametallic Group 6
(Fischer) Carbene Complexes
M. P. LÓPEZ-ALBERCA, M. J. MANCHEÑO, I. FERNÁNDEZ, M. GÓMEZ-GALLEGO, M. A.
SIERRA, C. HEMMERT, H. GORNITZKA
Eur. J. Inorg. Chem., 842–849 (2011)
207
Encaging the Verkade’s Superbases: Thermodynamic and Kinetic Consequences
P. D. RAYTCHEV, A. MARTINEZ, H. GORNITZKA, J.-P. DUTASTA
J. Am. Chem. Soc., 133, 2157-2159 (2011)
206
1,3-Dipole Behavior of Phosphagermaallene Tip(tBu)Ge=C=PMes* Leading to a
Phosphagermaheterocyclic Carbene
D. GHEREG, E. ANDRÉ, J.-M. SOTIROPOULOS, K. MIQUEU, H. GORNITZKA, J. ESCUDIÉ
Angew. Chem. Int. Ed., 49, 8704-8707 (2010)
205
The Reactivity of Phosphagermaallene Tip(t-Bu)Ge=C=PMes* with Doubly and
Triply Bonded Nitrogen Compounds
D. GHEREG, H. GORNITZKA, J. ESCUDIÉ, S. LADEIRA
Inorg. Chem., 49, 10497–10505 (2010)
204
Reactions of Germenes with Some para-Quinones: Formation of a Tricyclic
Compound from 1,4-Benzoquinone Undergoing an Unexpected Rearrangement
D. GHEREG, E. ANDRÉ, S. ECH-CHERIF EL KETTANI, N. SAFFON, M. LAZRAQ, H.
RANAIVONJATOVO, H. GORNITZKA, K. MIQUEU, J.-M. SOTIROPOULOS, J. ESCUDIÉ
Organometallics, 29, 4849–4857 (2010)
203
Chiral Variation of a Hybrid Bis(carbene-amido) Ligand System
F. JEAN-BAPTISTE DIT DOMINIQUE, H. GORNITZKA, C. HEMMERT
Organometallics, 29, 2868–2873 (2010)
202
The Reactivity of Phosphagermaallene Mes*P=C=Ge(t-Bu)Tip toward Aldehydes
and Ketones: an Experimental and Theoretical Study
F. OUHSAINE, E. ANDRÉ, J.M. SOTIROPOULOS, J. ESCUDIÉ, H. RANAIVONJATOVO, H.
GORNITZKA, N. SAFFON, K. MIQUEU, M. LAZRAQ
Organometallics, 29, 2566–2578 (2010)
201
Facile Derivatization of a “Chemo-active” NHC Incorporating an Enolate
Backbone and Relevant Tuning of Its Electronic Properties
L. BENHAMOU, N. VUJKOVIC, V. CÉSAR, H. GORNITZKA, N. LUGAN, G. LAVIGNE
Organometallics, 29, 2616–2630 (2010)
200
Reactions of germenes with various naphthoquinones controlled by substituent
effects
D. GHEREG, H. GORNITZKA, H. RANAIVONJATOVO, J. ESCUDIÉ
Dalton Trans., 39, 2016–2022 (2010)
199
Controlling Helical Chirality in Atrane Structures: Solvent-Dependent Chirality
Sense in Hemicryptophane-Oxidovanadium(V) Complexes
A. MARTINEZ, V. ROBERT, H. GORNITZKA, J.-P. DUTASTA
Chem. Eur. J., 16, 520–527 (2010)
198
An isolable o-quinodimethane and its fixation of molecular oxygen to give an
endoperoxide
D. GHEREG, S. ECH-CHERIF EL KETTANI, M. LAZRAQ, H. RANAIVONJATOVO, W. W.
SCHOELLER, J. ESCUDIÉ, H. GORNITZKA
Chem. Commun., 4821–4823 (2009)
197
Antimalarial Activity of Simalikalactone E, a New Quassinoid from Quassia amara
L. (Simaroubaceae)
N. CACHET, F. HOAKWIE, S. BERTANI, G. BOURDY, E. DEHARO, D. STIEN, E. HOUEL,
H. GORNITZKA, J. FILLAUX, S. CHEVALLEY, A. VALENTIN, V. JULLIAN
Antimicrob. Agents Chemother., 53, 4393–4398 (2009)
196
Imidazol-2-ylidene-4-olate: an anionic N-heterocyclic carbene pre-programmed for
further derivatization
L. BENHAMOU, V. CESAR, H. GORNITZKA, N. LUGAN, G. LAVIGNE
Chem. Commun., 4720–4722 (2009)
195
From a Stannene and Quinones to Various Tin-Containing Heterocycles
D. GHEREG, H. RANAIVONJATOVO, N. SAFFON, H. GORNITZKA, J. ESCUDIÉ
Organometallics, 28, 2294-2299 (2009)
194
N,N’ and N,O chelated phosphenium cations containing aminotroponiminate or
aminotroponate units
L.-C. POP, N. KATIR, A. CASTEL, L. SILAGHI-DUMITRESCU, F. DELPECH, I. SILAGHIDUMITRESCU, H. GORNITZKA, D. MACLEOD-CAREY, N. SAFFON
J. Organomet. Chem., 694, 1562-1566 (2009)
193
A stereoselective synthetic entry to β-substituted α-[(trans)-vinyl] phosphonamides
O. ILLA, S. CELIS, A. EL-KAZZI, H. GORNITZKA, A. BACEIREDO, V. BRANCHADELL, R.
M. ORTUÑO
Tetrahedron, 65, 2451-2454 (2009)
192
Heterobinuclear s-Indacene Rhodium Complexes: Synthesis and Characterization
C. ADAMS, C. MORALES-VERDEJO, V. MORALES, D. MACLEOD-CAREY,
J. M. MANRÍQUEZ, I. CHÁVEZ, A. MUÑOZ-CASTRO, F. DELPECH, A. CASTEL,
H. GORNITZKA, M. RIVIÈRE-BAUDET, P. RIVIÈRE, E. MOLINS
Eur. J. Inorg. Chem., 784-791 (2009)
191
vic-Dichlorodiphosphapropenes - Synthesis and Coordination Ability
R. SEPTELEAN, G. NEMES, J. ESCUDIÉ, I. SILAGHI-DUMITRESCU,
H. RANAIVONJATOVO, P. PETRAR, H. GORNITZKA, L. SILAGHI-DUMITRESCU,
N. SAFFON
Eur. J. Inorg. Chem., 628-634 (2009)
190
Dinuclear gold(I) and gold(III) complexes of bridging functionalized
bis(N-heterocyclic carbene) ligands: synthesis, structural, spectroscopic and
electrochemical characterizations
F. JEAN-BAPTISTE DIT DOMINIQUE, H. GORNITZKA, A. SOURNIA-SAQUET,
C. HEMMERT
Dalton Trans., 340-352 (2009)
189
Novel N-Phosphonio Imine-Catalyzed Epoxidation Reactions
D. PRIEUR, A. EL KAZZI, T. KATO, H. GORNITZKA, A. BACEIREDO
Org. Lett., 10, 2291-2294 (2008)
188
An unexpected epoxidation of benzil derivatives in their reaction with a germene
S. ECH-CHERIF EL KETTANI, M. LAZRAQ, F. OUHSAINE, H. GORNITZKA,
H. RANAIVONJATOVO, J. ESCUDIÉ
Org. Biomol. Chem., 6, 4064-4066 (2008)
187
Chlorophosphaalkenyl- and chloroalkenylstibanes
L. BAIGET, R. EL AYOUBI, H. RANAIVONJATOVO, J. ESCUDIÉ , H. GORNITZKA
J. Organomet. Chem., 693, 2293-2298 (2008)
186
N-Functionalised heterocyclic dicarbene complexes of silver: Synthesis and
structural studies
F. JEAN-BAPTISTE DIT DOMINIQUE, H. GORNITZKA, C. HEMMERT
J. Organomet. Chem., 693, 579-583 (2008)
185
Synthesis of “Trioxaquantel”® Derivatives as Potential New Antischistosomal
Drugs
S. A.-L. LAURENT, J. BOISSIER, F. COSLEDAN, H. GORNITZKA, A. ROBERT,
B. MEUNIER
Eur. J. Org. Chem., 895-913 (2008)
184
A Synthetic Equivalent of a Germanone Derivative
E. BONNEFILLE, S. MAZIERES, C. BIBAL, N. SAFFON, H. GORNITZKA, C. COURET
Eur. J. Inorg. Chem., 4242-4247 (2008)
183
A Nearly Planar Stannene with a Reactive Tin-Carbon Double Bond
ABDOUL FATAH, R. EL AYOUBI, H. GORNITZKA, H. RANAIVONJATOVO, J. ESCUDIÉ
Eur. J. Inorg. Chem., 2007-2013 (2008)
182
Germylenes and Stannylenes with Chelating Anilido–Imine Ligands: Syntheses,
Structures and Reactivity
A. MCHEIK, N. KATIR, A. CASTEL, H. GORNITZKA, S. MASSOU, P. RIVIÈRE, T. HAMIEH
Eur. J. Inorg. Chem., 5397-5403 (2008)
181
Preparation and Study of New Poly-8-Hydroxyquinoline Chelators for an antiAlzheimer Strategy
C. DERAEVE, C. BOLDRON, A. MARAVAL, H. MAZARGUIL, H. GORNITZKA,
L. VENDIER, M. PITIE, B. MEUNIER
Chem. Eur. J., 14, 682-696 (2008)
180
Stereoselective coordination of ditopic phospholyl-azahelicenes: a novel approach
towards structural diversity in chiral π-conjugated assemblies
W. SHEN, S. GRAULE, J. CRASSOUS, C. LESCOP, H. GORNITZKA, R. REAU
Chem. Commun., 850-852
850
(2008)
179
Palladium–Oxygen
Oxygen and Palladium–Arene
Palladium Arene Interactions in Complexes Derived from
Biaryl Aminocarbenes: Comparison with Biaryl Phosphanes
J. VIGNOLLE, H. GORNITZKA, B.
B DONNADIEU, D. BOURISSOU, G. BERTRAND
Angew. Chem. Int. Ed., 47, 2271-2274 (2008)
178
Synthesis and characterization of the first Arsanylbis(methylene)phosphorane
(Me3Si)2C=P(Mes*)=C(Cl)-As(F)Mes*
C=P(Mes*)=C(Cl)
P. M. PETRAR, G. NEMES,
NEM
L. SILAGHI-DUMITRESCU, I. SILAGHIDUMITRESCU,
HIDUMITRESCU,
J. ESCUDIÉ, H. GORNITZKA,
GORNI
H. RANAIVONJATOVO
Revue Roumaine de Chimie, 52(1-2), 45-49 (2007)
177
Activity-guided
guided isolation of antiplasmodial dihydrochalcones and flavanones from
Piper hostmannianum var. berbicense
B. PORTET, N. FABRE, V. ROUMY, H. GORNITZKA,
KA, G. BOURDY, S. CHEVALLEY,
CH
M. SAUVAIN, A. VALENTIN,
VALEN
C. MOULIS
Phytochemistry, 68,
68 1312-1320 (2007)
176
Ruthenium-Stabilized
Stabilized Low-Coordinate
Low
Phosphorus Atoms. p-Cymene
Cymene Ligand as
Reactivity Switch
R. MENYE-BIYOGO,
BIYOGO, F. DELPECH, A. CASTEL, V. PIMIENTA,
TA, H. GORNITZKA, P. RIVIÈRE
Organometallics, 26,
26 5091-5101 (2007)
175
New Digermylalkenes and Digermylalkynes: [1,3]-Chlorine
[1,3] Chlorine Shifts in
Organogermanium Chemistry?
G. NEMES, J. ESCUDIÉ,
ESCUDIÉ I. SILAGHI-DUMITRESCU, H. RANAIVONJATOVO,
VONJATOVO,
L. SILAGHI-DUMITRESCU,
DUMITRESCU, H. GORNITZKA
GORNI
Organometallics, 26,
26 5136-5139 (2007)
174
Versatile Reactivity of the Germene Mes2Ge=CR2 toward Esters and Related
Carbonyl Derivatives
S. ECH-CHERIF
CHERIF EL KETTANI, M.
M LAZRAQ, H. RANAIVONJATOVO,
NJATOVO, J. ESCUDIÉ,
H. GORNITZKA, F. OUHSAINE
OUH
Organometallics, 26,
26 3729-3734 (2007)
173
Palladate Salts from Chiral Pyridinium Ionic Liquids: Synthesis and Crystal
Structures
E. TOURNEUX, H. GORNITZKA,
GORN
J.-D. MARTY, N. LAUTH-DE
DE VIGUERIE
Molecules, 12,, 1940-1949
1940
(2007)
172
Transient Palladadiphosphanylcarbenes: Singlet Carbenes with an "Inverse"
Electronic Configuration (p 2 instead of 2) and Unusual Transannular MetalMetal
Carbene Interactions ( C Pd Donation and Pd C Back-donation)
donation)
J. VIGNOLLE, H. GORNITZKA,
GORN
L. MARON, W.W.. SCHOELLER, D. BOURISSOU,
BOUR
G. BERTRAND
J. Am. Chem. Soc., 129(4), 978-985 (2007)
171
Spirolactone iridoids might be responsible for the antileishmanial activity of a
Peruvian traditional remedy made with Himatanthus sucuuba (Apocynaceae)
D. CASTILLO, J. AREVALO, F. HERRERA, C. RUIZ, R. ROJAS, E. RENGIFO, A. VAISBERG,
O. LOCK, J.-L. LEMESRE, H. GORNITZKA, M. SAUVAIN
Journal of Ethnopharmacology, 112, 410-414 (2007)
170
Transient Amino-Hydrazino-Carbenes: A Radical Pathway for Intramolecular
1,2-Migration Reactions
X. CATTOËN, H. GORNITZKA, F.S. THAM, K. MIQUEU, D. BOURISSOU, G. BERTRAND
Eur. J. Org. Chem., 912-917 (2007)
169
Ring-Chain Tautomerism of Simplified Analogues of Isoniazid-NAD(P) Adducts:
an Experimental and Theoretical Study
T. DELAINE, V. BERNARDES-GENISSON, J.-L. STIGLIANI, H. GORNITZKA, B. MEUNIER,
J. BERNADOU
Eur. J. Org. Chem., 1624-1630 (2007)
168
1,3-Digermacyclobutanes with exocyclic C-P and C-P-S double bonds
P. M. PETRAR, G. NEMES, I. SILAGHI-DUMITRESCU, H. RANAIVONJATOVO,
H. GORNITZKA, J. ESCUDIÉ
Chem. Commun., 4149-4151 (2007)
167
Stable P-Heterocyclic Carbenes: Scope and Limitations
J.D. MASUDA, D. MARTIN, C. LYON-SAUNIER, A. BACEIREDO, H. GORNITZKA,
B. DONNADIEU, G. BERTRAND
Chem. Asian J., 2, 178-187 (2007)
166
Changes of the Membrane Lipid Organization Characterized by Means of a New
Cholesterol-Pyrene Probe
L. LE GUYADER, C. LE ROUX, S. MAZERES, H. GASPARD-ILOUGHMANE,
H. GORNITZKA, C. MILLOT, C. MINGOTAUD, A. LOPEZ
Biophysical Journal, 93(12), 4462-4473 (2007)
165
Synthesis of ferulic ester dimers, functionalisation and biological evaluation as
potential antiatherogenic and antiplasmodial agents
D. L. A. RAKOTONDRAMANANA, M. DELOMENÈDE, M. BALTAS, H. DURAN,
F. BEDOS-BELVAL, P. RASOANAIVO, A. NEGRE-SALVAYREC, H. GORNITZKA
Bioorg. Med. Chem., 15, 6018-6026 (2007)
164
Regio- and stereo-selectivity in the silylation of 2,6-diethyl-3,4,7,8-tetramethyl1,5-dihydro-s-indacene
M. DAHROUCH, F. BURGOS, A. CASTEL, I. CHAVEZ, H. GORNITZKA, J.M. MANRIQUEZ,
P. RIVIÈRE, M. RIVIÈRE-BAUDET, J. ALVAREZ, M. ONYSZCHUK
Appl. Organometal. Chem., 21, 31-38 (2007)
163
Thermal Valence Isomerization of 2,3-Diborata-1,4-diphosphoniabuta-1,3-dienes
to Bicyclo[1.1.0]butanes and Cyclobutane-1,3-diyls
J.-B. BOURG, A. RODRIGUEZ, D. SCHESCHKEWITZ, H. GORNITZKA, D. BOURISSOU,
G. BERTRAND
Angew. Chem. Int. Ed., 46, 5741-5745 (2007)
162
Unexpected opening of benzimidazole derivatives during 1,3-dipolar cycloaddition
B. EL AZZAOUI, B. RACHID, M.L. DOUMBIA, E.M. ESSASSI, H. GORNITZKA, J. BELLAN
Tetrahedron Lett., 47, 8807-8810 (2006)
161
Enforced η1-fluorenyl coordination to rhodium(I) with the [FluPPh2NPh]- ligand
C. FREUND, N. BARROS, H. GORNITZKA, B. MARTIN-VACA, L. MARON, D. BOURISSOU
Organometallics, 25, 4927-4930 (2006)
160
Synthesis and X-ray structure of a novel N '-ferrocenylmethyl-N 'phenylbenzohydrazide
B. TERKI, T. LANEZ, S. BELAIDI, H. GORNITZKA, A. OURARI
Asian J. Chem., 18, 2074-2080 (2006)
159
Synthesis and chemistry of aryloxygermylene-amine complexes
E. BONNEFILLE, S. MAZIERES, N. EL HAWI, H. GORNITZKA, C. COURET
J. Organomet. Chem., 691, 5619-5625 (2006)
158
New Rh derivatives of s-indacene active in dehydrogenative silylation of styrene
E. ESPONDA, C. ADAMS, F. BURGOS, I. CHAVEZ, J.M. MANRIQUEZ, F. DELPECH,
A. CASTEL, H. GORNITZKA, M. RIVIERE-BAUDET, P. RIVIERE
J. Organomet. Chem., 691, 3011-3017 (2006)
157
Diastereoselective Synthesis of Conformationally Restricted Dinucleotides
Featuring Canonical and Noncanonical α/β Torsion Angle Combinations (α,β-DCNA)
C. DUPOUY, I. LE CLEZIO, P. LAVEDAN, H. GORNITZKA, J.-M. ESCUDIER, A. VIGROUX
Eur. J. Org. Chem., 5515-5525 (2006)
156
Phosphavinylidene(oxo)phosphorane Mes*P(O)=C=PMes*: A diphosphaallene
featuring λ5σ3- and λ3σ2-phosphorus atoms
R. SEPTELEAN, H. RANAIVONJATOVO, G. NEMES, J. ESCUDIE,
I. SILAGHI-DUMITRESCU, H. GORNITZKA, L. SILAGHI-DUMITRESCU, S. MASSOU
Eur. J. Inorg. Chem., 4237-4241 (2006)
155
Cyclic carbodiphosphorane-diphosphinocarbene thermal interconversion
S. MARROT, T. KATO, F.P. COSSIO, H. GORNITZKA, A. BACEIREDO
Angew. Chem. Int. Ed., 45, 7447-7450 (2006)
154
Cyclic carbodiphosphoranes: Strongly nucleophilic sigma-donor ligands
S. MARROT, T. KATO, H. GORNITZKA, A. BACEIREDO
Angew. Chem. Int. Ed., 45, 2598-2601 (2006)
153
Rhodium(I) Complexes of a PBP Ambiphilic Ligand: Evidence for a Metal-Borane
Interaction
S. BONTEMPS, H. GORNITZKA, G. BOUHADIR, K. MIQUEU, D. BOURISSOU
Angew. Chem. Int. Ed., 45, 1611-1614 (2006)
152
Probing helix propensity of monomers within a helical oligomer
C. DOLAIN, J.-M. LEGER, N. DELSUC, H. GORNITZKA, I. HUC
PNAS, 102, 16146-16151 (2005)
151
Reactivity of the Germene Mes2Ge=CR2 with cumulative unsaturation-containing
compounds: Synthesis of new germanium heterocycles
S. ECH-CHERIF EL KETTANI, M. LAZRAQ, H. RANAIVONJATOVO, J. ESCUDIE,
C. COURET, H. GORNITZKA, A. ATMANI
Organometallics, 24, 5364-5368 (2005)
150
In Search of Cationic Germanium(II)-Transition Metal Complexes L2Ge+W(CO)5
and L2Ge+W(CO)4Ge+L2
I. SAUR, S. GARCZIA ALONSO, H. GORNITZKA, V. LEMIERRE, A. CHROSTOWSKA,
J. BARRAU
Organometallics, 24, 2988-2996 (2005)
149
Studies on the 4-benzoylpyridine-3-carboxamide entity as a fragment model of the
Isoniazid–NAD adduct
S. BROUSSY, V. BERNARDES-GENISSON, H. GORNITZKA, J. BERNADOU, B. MEUNIER
Org. Biomol. Chem., 3, 666-669 (2005)
148
A stable (amino)(phosphino)carbene as bidentate ligand for palladium and nickel
complexes: Synthesis, structure, and catalytic activity
E. TEUMA, C. LYON-SAUNIER, H. GORNITZKA, G. MIGNANI, A. BACEIREDO,
G. BERTRAND
J. Organomet. Chem., 690, 5541-5545 (2005)
147
Synthesis and activity of macrocyclized chiral Mn(III)–Schiff-base epoxidation
catalysts
A. MARTINEZ, C. HEMMERT, H. GORNITZKA, B. MEUNIER
J. Organomet. Chem., 690, 2163-2171 (2005)
146
Constrained Nucleic Acids (CNA). Part 2. Synthesis of Conformationally
Restricted Dinucleotide Units Featuring Noncanonical α/β/γ or δ/ε/ζ Torsion
Angle Combinations
I. LE CLEZIO, H. GORNITZKA, J.-M. ESCUDIER, A. VIGROUX
J. Org. Chem., 70, 1620-1629 (2005)
145
Evidence for Radical Fragmentations from Persistent Singlet Carbenes
X. CATTOEN, K. MIQUEU, H. GORNITZKA, D. BOURISSOU, G. BERTRAND
J. Am. Chem. Soc., 127, 3292-3293 (2005)
144
Chiral molecular imprinting in liquid-crystalline network
J.-D. MARTY, H. GORNITZKA, M. MAUZAC
Eur. Phys. J. , E17, 515-520 (2005)
143
A Surprisingly Stable 1-(Chlorosilyl)-2-phosphaethenyllithium Compound,
RCl2SiC(Li)=PMes*
G. CRETIU NEMES, H. RANAIVONJATOVO, J. ESCUDIE, I. SILAGHI-DUMITRESCU,
L. SILAGHI-DUMITRESCU, H. GORNITZKA
Eur. J. Inorg. Chem., 1109-1113 (2005)
142
C-Phosphoniophosphaalkenes as Precursors of 1σ4,3σ2-Diphosphaallenes: Scope
and Limitations
D. MARTIN, H. GORNITZKA, A. BACEIREDO, G. BERTRAND
Eur. J. Inorg. Chem., 2619-2624 (2005)
141
Preparation of Cyclo-Phen-Type Ligands: Chelators of Metal Ions as Potential
Therapeutic Agents in the Treatment of Neurodegenerative Diseases
C. BOLDRON, I. VAN DER AUWERA, C. DERAEVE, H. GORNITZKA, S. WERA, M. PITIE,
F. VAN LEUVEN, B. MEUNIER
ChemBioChem, 6, 1976-1980 (2005)
140
Stereocontrolled formation of substituted imidazolidines in the reaction between Nmetallated azomethine ylides and isocyanates
E. ERKIZIA, E. ALDABA, Y. VARA, A. ARRIETA, H. GORNITZKA, F.P. COSSIO
ARKIVOC, IX, 189-199 (2005)
139
Dimerization of a Cyclo-1σ4,3σ2,4σ2-Triphosphapentadienyl Radical: Evidence for
Phosphorus-Phosphorus Odd-Electron Bonds
T. KATO, H. GORNITZKA, W.W. SCHOELLER, A. BACEIREDO, G. BERTRAND
Angew. Chem. Int. Ed. Engl., 44, 5497-5500 (2005)
138
A Stable P-Heterocyclic Carbene
D. MARTIN, A. BACEIREDO, H. GORNITZKA, W.W. SCHOELLER, G. BERTRAND
Angew. Chem. Int. Ed., 44, 1700-1703 (2005)
137
N-aryl anions: Half way between amides and carbanions
R. VON BÜLOW, S. DEUERLEIN, T. STEY, R. HERBST-IRMER, H. GORNITZKA,
D. STALKE
Z. Naturforschung Sec. B, 59, 1471-1479 (2004)
136
Reaction of a stable aminoarylcarbene with 2-chloroacrylonitrile: dearomatizing
cyclization rather than cyclopropanation
S. SOLE, X. CATTOEN, H. GORNITZKA, D. BOURISSOU, G. BERTRAND
Tetrahedron Lett., 45, 5391-5393 (2004)
135
Comparative electrochemical properties of fluorinated endoperoxides related to the
G-factor series
F. NAJJAR, F. FREVILLE, F. DESMOULIN, L. GORRICHON, M. BALTAS, H. GORNITZKA,
T. TZEDAKISC, C. ANDRE-BARRES
Tetrahedron Lett., 45, 6919-6922 (2004)
134
Varied Reactivity of the Germene Mes2Ge=CR2 toward Nitriles
S. ECH-CHERIF EL KETTANI, M. LAZRAQ, H. RANAIVONJATOVO, J. ESCUDIE,
C. COURET, H. GORNITZKA, N. MERCERON
Organometallics, 23, 5062-5065 (2004)
133
Synthesis, Structures, and Reactivity of Mono- and Bis(ferrocenyl)-Substituted
Group 14 Metallocenes
M. JOUDAT, A. CASTEL, F. DELPECH, P. RIVIERE, A. MCHEIK, H. GORNITZKA,
S. MASSOU, A. SOURNIA-SAQUET
Organometallics, 23, 3147-3152 (2004)
132
α, β-(Phosphino)(aminocarbene) and α, ω-(phosphino)(oxyaminocarbene): new
bidentate ligands for transition metal complexes
N. MERCERON-SAFFON, H. GORNITZKA, A. BACEIREDO, G. BERTRAND
J. Organomet. Chem., 689, 1431-1435 (2004)
131
Amino-Aryl-Carbenes: Alternative Ligands for Transition Metals?
X. CATTOEN, H. GORNITZKA, D. BOURISSOU, G. BERTRAND
J. Am. Chem. Soc., 126, 1342-1343 (2004)
130
Radical-Type Reactivity of the 1,3-Dibora-2,4-Diphosphoniocyclobutane-1,3-diyl
H. AMII, L. VRANICAR, H. GORNITZKA, D. BOURISSOU, G. BERTRAND
J. Am. Chem. Soc., 126, 1344-1345 (2004)
129
A stable distannirane
L. BAIGNET, H. RANAIVONJATOVO, J. ESCUDIE, H. GORNITZKA
J. Am. Chem. Soc., 126, 11792-11793 (2004)
128
Switching of Chiral Induction in Helical Aromatic Oligoamides Using Solid StateSolution State Equilibrium
H. JIANG, C. DOLAIN, J.-M. LEGER, H. GORNITZKA, I. HUC
J. Am. Chem. Soc., 126, 1034-1035 (2004)
127
Reactivity of 2,6-diethyl-4,8-dimethyl-1,5-dioxo-s-hydrindacene towards radical,
anionic and cationic germylation
A. EL KADIB, A. CASTEL, F. DELPECH, P. RIVIERE, M. RIVIERE-BAUDET,
H. GORNITZKA, P. AGUIRRE, J.M. MANRIQUEZ, I. CHAVEZ, D. ABRIL
Inorg. Chim. Acta, 357, 1256-1264 (2004)
126
Heterocyclisation of ferrocenyl- and benzenetricarbonyl
chromiumcyclopentadienes with o-quinone. Evidence for a SET route
M. JOUDAT, J. ROUZAUD, A. CASTEL, F. DELPECH, P. RIVIERE, H. GORNITZKA,
S. MASSOU
Inorg. Chim. Acta, 357, 259-264 (2004)
125
Synthesis and Reactivity of a New Nonacarbon Chain Carboxonium Salt - Access
to a New Class of Streptocyanine Dyes
A. IZQUIERDO, V. GUIEU, H. GORNITZKA, Y. MADAULE, C. PAYRASTRE
Eur. J. Org. Chem., 2317-2320 (2004)
124
Syntheses, Structures, Bonding and Photoelectron Spectra of ‘‘Push-Pull’’Substituted P-[2,6-Bis(trifluoromethyl)phenyl]-σ2λ3-iminophosphanes
K. MIQUEU, J.-M. SOTIROPOULOS, G. PFISTER-GUILLOUZO, V.L. RUDZEVICH,
H. GORNITZKA, V. LAVALLO, V.D. ROMANENKO
Eur. J. Inorg. Chem., 2289-2300 (2004)
123
Structural Characterization of Bismuth(III) and Antimony(III) Chlorotriflates: Key
Intermediates in Catalytic Friedel-Crafts Transformations
S. MAZIERES, C. LE ROUX, M. PEYRONNEAU, H. GORNITZKA, N. ROQUES
Eur. J. Inorg. Chem., 2823-2826 (2004)
122
Synthesis and Antimalarial Activity of Trioxaquine Derivatives
O. DECHY-CABARET, F. BENOIT-VICAL, C. LOUP, A. ROBERT, H. GORNITZKA,
A. BONHOURE, H. VIAL, J.-F. MAGNAVAL, J.-P. SEGUELA, B. MEUNIER
Chem. Eur. J., 10, 1625-1636 (2004)
121
Stable Optically Pure Phosphino(silyl)carbenes: Reagents for Highly
Enantioselective Cyclopropanation Reactions
J. KRYSIAK, C. LYON, A. BACEIREDO, H. GORNITZKA, M. MIKOLAJCZYK,
G. BERTRAND
Chem. Eur. J., 10, 1982-1986 (2004)
120
σ-Bond Stretching: A Static Approach for a Dynamic Process
D. SCHESCHKEWITZ, H. AMII, H. GORNITZKA, W.W. SCHOELLER, D. BOURISSOU,
G. BERTRAND
Angew. Chem. Int. Ed., 43, 585-587 (2004)
119
Crystal structure of a model Hydroxyspirophosphorane intermediary compound
involving cyclic phosphoric acid esters
A. MUNOZ, H. GORNITZKA
Phosphorus sulfur silicon relat. elem., 178, 55-60 (2003)
118
Synthesis of carbenes through substitution reactions at a carbene center
N. MERCERON-SAFFON, A. BACEIREDO, H. GORNITZKA, G. BERTRAND
Science, 301, 1223-1225 (2003)
117
Heteronuclear multiple bonding between heavier group 14 and 16 elements. A new
class of germylated compounds, the germanethiocarbamyl and
germaselenocarbamyl chlorides L2(Cl)GeY (Y=S, Se)
I. SAUR, G. RIMA, H. GORNITZKA, K. MIQUEU, J. BARRAU
Organometallics, 22, 1106-1109 (2003)
116
New Reactivity of Chromium(0) Fischer Carbene Complexes: Unprecedented
Insertion of a Carbene Ligand into an Active B-H Bond
P. RAMIREZ-LOPEZ, M.A. SIERRA, M. GOMEZ-GALLEGO, M.J. MANCHENO,
H. GORNITZKA
Organometallics, 22, 5092-5099 (2003)
115
The first coordination of an (α-diazo)phosphine to a transition-metal center
E. DESPAGNET-AYOUB, H. GORNITZKA, J. FAWCETT, P.W. DEYER, D. BOURISSOU,
G. BERTRAND
Organometallics, 22, 1358-1360 (2003)
114
Heteronuclear bonding between heavier group 14 elements and transition metals:
novel halogermylene- and stannylene transitionmetal complexes L2(X)MM’L’n
[L2=PhNC(Me)CHC(Me)NPh; X=Cl,I; M=Ge,Sn; M’L’n=W(CO)5, Fe(CO)4]
I. SAUR, G. RIMA, K. MIQUEU, H. GORNITZKA, J. BARRAU
J. Organomet. Chem., 672, 77-85 (2003)
113
Synthesis and structural characterization of unusual amido samarium(III)
complexes
B. MARTIN-VACA, A. DUMITRESCU, H. GORNITZKA, D. BOURISSOU, G. BERTRAND
J. Organomet. Chem., 682, 263-266 (2003)
112
Stereoselective synthesis of phosphoranyl aryloxiranes through the addition of a
nucleophilic stable carbene to aromatic aldehydes
O. ILLA, H. GORNITZKA, A. BACEIREDO, G. BERTRAND, V. BRANCHADELL,
R.M. ORTUNO
J. Org. Chem., 68, 7707-7710 (2003)
111
Transient azomethine-ylides from a stable amino-carbene and an aldiminium salt
X. CATTOEN, S. SOLE, C. PRADEL, H. GORNITZKA, K. MIQUEU, D. BOURISSOU,
G. BERTRAND
J. Org. Chem., 68, 911-914 (2003)
110
(Phosphino)(aryl)carbenes: Effect of aryl substituents on their stabilization mode
E. DESPAGNET-AYOUB, S. SOLE, H. GORNITZKA, A.B. ROZHENKO, W.W. SCHOELLER,
D. BOURISSOU, G. BERTRAND
J. Am. Chem. Soc., 125, 124-130 (2003)
109
Reactions of a stable (phosphanyl)(silyl)carbene with aliphatic aldehydes: [2+1]
versus [2+2] addition to a carbonyl group
O. ILLA, H. GORNITZKA, V. BRANCHADELL, A. BACEIREDO, G. BERTRAND,
R.M. ORTUNO
Eur. J. Org. Chem., 3147-3152 (2003)
108
Synthesis and Reactivity of a new heptacarbon chain carboxonium salt - Access to
a new class of streptocyanine dyes
A. IZQUIERDO, C. PAYRASTRE, H. GORNITZKA, Y. MADAULE
Eur. J. Org. Chem., 2371-2374 (2003)
107
(Aryl)(phosphanyl)carbene: Ground and excited state reactions
E. DESPAGNET-AYOUB, H. GORNITZKA, D. BOURISSOU, G. BERTRAND
Eur. J. Org. Chem., 2039-2042 (2003)
106
DNA cleavage by copper complexes of 2- and 3-Clip-Phen derivatives
M. PITIE, C. BOLDRON, H. GORNITZKA, C. HEMMERT, B. DONNADIEU, B. MEUNIER
Eur. J. of Inorg. Chem., 528-540 (2003)
105
A solid state study of eight-coordinate lanthanide(III) complexes (Ln=Eu, Ga, Tb,
Dy) with 1-hydroxy-2-pyridinone
C. TEDESCHI, J. AZEMA, H. GORNITZKA, P. TISNES, C. PICARD
Dalton Trans., 1738-1745 (2003)
104
The use of germene for the synthesis of esters of α-germyl-substituted α-amino
acid and α-aminophosphonic acid
S. ECH-CHERIF EL KETTANI, J. ESCUDIÉ, C. COURET, H. RANAIVONJATOVO,
M. LAZRAQ, M. SOUFIAOUI, H. GORNITZKA, G.C. NEMES
Chem. Commun., 1662-1663 (2003)
103
Crystal structure of the dimeric β-cyclodextrin complex 1,12-dodecandiol
T. BOJINOVA, H. GORNITZKA, N. LAUTH-DE VIGUERIE, I. RICO-LATTES
Carbohydr. Res., 338, 781-785 (2003)
102
Ruthenium-Stabilized Low-Coordinate Phosphorus Atoms: Structural Evidence for
Monomeric Metaphosphonate
R. MENYE-BIYOGO, F. DELPECH, A. CASTEL, H. GORNITZKA, P. RIVIERE
Angew. Chem. Int. Ed., 42, 5610-5612 (2003)
101
Spirophosphoranes D' α-cetoacides. Structure cristalline. Induction asymetrique
A. MUNOZ, H. GORNITZKA, A. ROCHAL
Phosphorus sulfur silicon relat. elem., 177, 1255-1269 (2002)
100
A comparative study on the 1,3-dipolar cycloadditions of diazomethane and
bis(diisopropylamino)phosphinodiazomethane to chiral electron-deficient olefins:
reactivity and diastereoselectivity
O. ILLA, E. MURAY, D. AMSALLEM, A.G. MOGLIONI, H. GORNITZKA,
V. BRANCHADELL, A. BACEIREDO, R.M. ORTUNO
Tetrahedron: Asymmetry, 13, 2593-2603 (2002)
99
Singlet diradicals: from transition states to crystalline compounds
D. SCHESCHKEWITZ, H. AMII, H. GORNITZKA, W.W. SCHOELLER, D. BOURISSOU,
G. BERTRAND
Science, 295, 1880-1881 (2002)
98
New arylchlorogermylenes stabilized by two ortho side-chain donor ligands
C. BIBAL, S. MAZIERES, H. GORNITZKA, C. COURET
Polyhedron, 21, 2827-2834 (2002)
97
From chlorogermylenes to stable hydroxy- and siloxy-germylene-tungsten
complexes
C. BIBAL, S. MAZIERES, H. GORNITZKA, C. COURET
Organometallics, 21, 2940-2943 (2002)
96
From the new arsaalkene ArAs=C(Br)SiMe3 to the first stable arsaallene,
ArAs=C=CR2 (Ar=2,4,6-tri-tert-butylphenyl, CR2 = fluorenylidene)
M. BOUSLIKHANE, H. GORNITZKA, H. RANAIVONJATOVO, J. ESCUDIÉ
Organometallics, 21, 1531-1533 (2002)
95
Synthesis and structure of 1,2,4-triazol-2-ium-5-ylidene complexes of Hg(II),
Pd(II), Ni(II), Ni(0), Rh(I) and Ir(I)
C. BURON, L. STELZIG, O. GUERRET, H. GORNITZKA, V. ROMANENKO, G. BERTRAND
J. Organomet. Chem., 664, 70-76 (2002)
94
The first stable 3,1-germaphosphaallene Tip(t-Bu)Ge=C=PAr
Y. EL HAROUCH, H. GORNITZKA, H. RANAIVONJATOVOJ. ESCUDIÉ
J. Organomet. Chem., 643-644, 202-208 (2002)
93
Phosphane- and phosphorane Janus Head ligands in metal coordination
F. BAIER, Z. FEI, H. GORNITZKA, A. MURSO, S. NEUFELD, M. PFEIFFER,
I. RÜDENAUER, A. STEINER, T. STEY, D. STALKE
J. Organomet. Chem., 661, 111-127 (2002)
92
Some aspects of chemistry of the N → Si chelated aryloxydihydrosilanes
R(ArO)SiH2(R=Ph, ArO) and of the 2,2-diaryloxytrisilane
(Me3Si)2Si(OAr)2{ArO=2,4,6-[(CH3)2NCH2]3C6H2O}
A.A.E. AHDAB, G. RIMA, H. GORNITZKA, J. BARRAU
J. Organomet. Chem., 658, 94-105 (2002)
91
New linked di-germanocenes and di-stannocenes
J. ROUZAUD, M. JOUDAT, A. CASTEL, F. DELPECH, P. RIVIÈRE, H. GORNITZKA,
J.M. MANRIQUEZ, I. CHAVEZ
J. Organomet. Chem., 651, 44-51 (2002)
90
Synthesis and rearrangement of diphosphorus analogues of amidinium salts
T. KATO, H. GORNITZKA, A. BACEIREDO, WW. SCHOELLER, G. BERTRAND
J. Am. Chem. Soc., 124, 2506-2512 (2002)
89
Stable (aryl)(phosphino)carbenes: New ligands for transition metals
E. DESPAGNET, K. MIQUEU, H. GORNITZKA, P.W. DEYER, D. BOURISSOU,
G. BERTRAND
J. Am. Chem. Soc., 124, 11834-11835 (2002)
88
A new oligomeric complex of cyclic hydrogenphosphonates with calcium
perchlorate
E. SUTRA, L. LAMANDE, H. GORNITZKA, J. BELLAN
Eur. J. Inorg. Chem., 2727-2729 (2002)
87
A crystalline phosphenium salt featuring the electron-withdrawing 2,6bis(trifluoromethyl)phenyl group
A. DUMITRESCU, H. GORNITZKA, W.W. SCHOELLER, D. BOURISSOU, G. BERTRAND
Eur. J. Inorg. Chem., 1953-1956 (2002)
86
Zinc(II), samarium(III) and tin(II) complexes featuring a tridentate nitrogen donor
for the ring-opening copolymerization of (D,L)-lactide and glycolide
A. DUMITRESCU, B. MARTIN-VACA, H. GORNITZKA, J.-B. CAZAUX, D. BOURISSOU,
G. BERTRAND
Eur. J. Inorg. Chem., 1948-1951 (2002)
85
A rare example of a rearrangement involving four structural isomers: αphosphinonitrile/C- phosphinoketenimine/1-aza-4-phosphabutadiene/1,2-dihydro1,2-azaphosphete
D. AMSALLEM, S. MAZIERES, V. PIQUET-FAURÉ, H. GORNITZKA, A. BACEIREDO,
G. BERTRAND
Chem. Commun., 5306-5311 (2002)
84
C-Phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents
N. MERCERON, A. BACEIREDO, H. GORNITZKA, G. BERTRAND
Chem. Commun., 2250-2251 (2002)
83
Hydroxy-substituted oligopyridine dicarboxamide helical foldamers
I. HUC, V. MAURIZOT, H. GORNITZKA, J.-M. LÉGER
Chem. Commun., 578-579 (2002)
82
The first "naked" primary phosphanide anion [ArPH]V.L. RUDZEVICH, H. GORNITZKA, K. MIQUEU, J.-M. SOTIROPOULOS,
G. PFISTER-GUILLOUZO, V.D. ROMANENKO, G. BERTRAND
Angew. Chem. Int. Ed. Engl., 41, 1193-1195 (2002)
81
Stable non-push-pull phosphanylcarbenes: NMR spectroscopic characterization of
a methylcarbene
E. DESPAGNET, H. GORNITZKA, A.B. ROZHENKO, W.W. SCHOELLER, D. BOURISSOU,
G. BERTRAND
Angew. Chem. Int. Ed. Engl., 41, 2835-2837 (2002)
80
Structure and properties of BETS salts: κ-(BETS)8(Cu2Cl6)(CuCl4), θ(BETS)2(CuCl2) and (BETS)2(CuCl4)
I. MALFANT, T. COURCET, C. FAULMANN, P. CASSOUX, H. GORNITZKA, F.GRANIER,
M.-L. DOUBLET, P. GUIONNEAU, J.A.K. HOWARD, N.D. KUSHCH, A. KOBAYASHI
C. R. Acad. Sci., Sér. IIc, Chim., 149-160 (2001)
79
(Amino)(aryl)carbenes : stable singlet carbenes featuring a spectator substituent
S. SOLE, H. GORNITZKA, W.W. SCHOELLER, D. BOURISSOU, G. BERTRAND
Science, 292, 1901-1903 (2001)
78
An effective and selective route to 1,5-dihydropolyalkylated s-indacenes.
Characterization of their mono and di-anions by silylation. Structure of trans-1,5bis(trimethylsilyl) 2,6-diethyl s-indacene.
M. DAHROUCH, P. JARA, L. MENDEZ, Y. PORTILLA, D. ABRIL, G. ALFONSO, I. CHAVEZ,
J.M. MANRIQUEZ, M. RIVIÈRE-BAUDET, P. RIVIÈRE, A. CASTEL, J. ROUZAUD,
H. GORNITZKA
Organometallics, 20, 5591-5597 (2001)
77
New routes to diarsenes and arsaphosphenes involving fluorinated arsines
M. BOUSLIKHANE, H. GORNITZKA, J. ESCUDIE, H. RANAIVONJATOVO
J. Organomet., Chem., 619, 275-279 (2001)
76
Three coordinate divalent group 14 element compounds with a β-diketiminate as
supporting ligand L2MX [L2=PhNC(Me)CHC(Me)NPh, X=Cl, I; M = Ge, Sn]
A. AKKARI, J.J. BYRNE, I. SAUR, G. RIMA, H. GORNITZKA, J. BARRAU
J. Organomet. Chem., 622, 190-198 (2001)
75
Synthesis and characterization of 2,4,6-tris[(dimethylamino)methyl]
phenoxysilicon compounds
A. AKKARI-EL AHDAB, G. RIMA, H. GORNITZKA, J. BARRAU
J. Organomet. Chem., 636, 96-107 (2001)
74
The first asymmetric cyclopropanation reactions involving a stable carbene
J. KRYSIAK, T. KATO, H. GORNITZKA, A. BACEIREDO, M. MIKOLAJCZYK,
G. BERTRAND
J. Org. Chem., 66, 8240-8242 (2001)
73
Preparation, characterization and crystal structures of manganese(II), iron(III) and
copper(II) complexes of the bis[di-1,1-(2-pyridyl)ethyl] amine (BDPEA) ligand;
evaluation of their DNA cleavage activities
C. HEMMERT, M. PITIE, M. RENZ, H. GORNITZKA, S. SOULET, B. MEUNIER
J. Biol. Inorg. Chem., 6, 14-22 (2001)
72
Formation of the monoanion [Ar*P(BH3)(µ-BH2)2H]- with a symmetrically
bridging hydride from the attempted synthesis of the dianion [Ar*P(BH3)3]2V. L. RUDZEVICH, H. GORNITZKA, V. ROMANENKO, G. BERTRAND
Chem. Commun., 1634-1635 (2001)
71
A route to a germanium-carbon triple bond: first chemical evidence for a germyne
C. BIBAL, S. MAZIÈRES, H. GORNITZKA, C. COURET
Angew. Chem. Int. Ed. Engl., 40, 952-954 (2001)
70
N-germyl derivatives of 4-nitrophenylamine: germylamines, stable germa-imine
F. EL BAZ, M. RIVIÈRE-BAUDET, C. CHAZALETTE, H. GORNITZKA
Phosphorus sulfur silicon relat. elem., 163, 121-142 (2000)
69
Trimesitylgermylcarbodiimid lithium, precursor for new mixed polymetallated
carbodiimide and polycarbodiimides of Ge, Si, Sb
M. RIVIÈRE-BAUDET, M. DAHROUCH, H. GORNITZKA
Phosphorus sulfur silicon relat. elem., 159, 23-35 (2000)
68
Stable versions of transient push-pull carbenes: extending lifetimes from
nanoseconds to weeks
C. BURON, H. GORNITZKA, V. ROMANENKO, G. BERTRAND
Science, 288, 834-836 (2000)
67
A cyclic carbanionic valence isomer of a carbocation: diphosphino analogs of
diaminocarbocations
T. KATO, H. GORNITZKA, A. BACEIREDO, W.W. SCHOELLER, G. BERTRAND
Science, 289, 754-756 (2000)
66
Preparation of axially chiral (racemic) spirosilanes and spirogermanes by selective
spirozirconation
V. DEJEAN, H. GORNITZKA, G. OBA, M. KOENIG, G. MANUEL
Organometallics, 19, 711-713 (2000)
65
Transmetalation reaction of dimethylzinc and (bis(2-pyridyl)methyl)lithium
H. GORNITZKA, C. HEMMERT, G. BERTRAND, M. PFEIFFER, D. STALKE
Organometallics, 19, 112-114 (2000)
64
Deprotonated iminophosphorane o-C6H4Ph2P=NSiMe3 as a novel ligand to
stabilize a diarylstannylene and -plumbylene via side arm donation
S. WINGERTER, H. GORNITZKA, R. BERTERMANN, S. K. PANDEY, J. ROCHA,
D. STALKE
Organometallics, 19, 3890-3894 (2000)
63
Ligand transfer reactions between Schiff base divalent group 14 element species
and titanium, nickel, boron and phosphorus halides
D. AGUSTIN, G. RIMA, H. GORNITZKA, J. BARRAU
Organometallics, 19, 4276-4282 (2000)
62
Synthesis and characterization of novel p-phenylene and p-biphenylene bridgedgermanocenes
J. ROUZAUD, A. CASTEL, P. RIVIÈRE, H. GORNITZKA, J.M. MANRIQUEZ
Organometallics, 19, 4678-4680 (2000)
61
Unprecedented amido-bridged dinuclear mixed-valence cobalt complexes: first
structure of a dinuclear µ-OMe Co(II)/Co(III) complex
C. HEMMERT, H. GORNITZKA, B. MEUNIER
New J. Chem., 24, 949-951 (2000)
60
The peculiar behavior of a diphosphirenium salt towards sodium η5-cyclo
pentadienyl (dicarbonyl)ferrate
T. KATO, O. POLISHCHUK, H. GORNITZKA, A. BACEIREDO, G. BERTRAND
J. Organomet. Chem., 613, 33-36 (2000)
59
1,2,4-Triazolium-5-ylidene and 1,2,4-triazol-3,5-diylidene as new ligands for
transition metals
O. GUERRET, S. SOLE, H. GORNITZKA, G. TRINQUIER, G. BERTRAND
J. Organomet. Chem., 600, 112-117 (2000)
58
Bis(trimesitylgermylcarbodiimido)germylene, trimesitylgermylcyanamide and
trimesitylgermylcarbodiimide
M. RIVIÈRE-BAUDET, M. DAHROUCH, H. GORNITZKA
J. Organomet. Chem., 595, 153-157 (2000)
57
The first diarsaallene ArAs=C=AsAr (Ar = 2,4,6-tri-t-butylphenyl)
M. BOUSLIKHANE, H. GORNITZKA, J. ESCUDIE, H. RANAIVONJATOVO, H. RAMDANE
J. Am. Chem. Soc. 122, 12880-12881 (2000)
56
On the electronic structure of (phosphino)(silyl)carbenes : single crystal X-ray
diffraction and ELF analyses
T. KATO, H. GORNITZKA, A. BACEIREDO, A. SAVIN, G. BERTRAND
J. Am. Chem. Soc., 122, 998-999 (2000)
55
Stereoselectivity and stereospecificity of cyclopropanation reactions with stable
(phosphanyl)(silyl)carbenes
S. GOUMRI-MAGNET, T. KATO, H. GORNITZKA, A. BACEIREDO, G. BERTRAND
J. Am. Chem. Soc., 122, 4464-4470 (2000)
54
Synthesis and characterization of group 14 elements - dithienylsulfur cycloadducts
and oligomers
S. FAURE, B. VALENTIN, J. ROUZAUD, H. GORNITZKA, A. CASTEL, P. RIVIERE
Inorg. Chim. Acta, 305, 46-52 (2000)
53
(Schiff base) divalent group 14 element species : manganese and iron complexes
(Salen)M=Mn(CO)2(η5-C5H5) (M14 = Ge, Sn, Pb) and (Salen)Sn=Fe(CO)4
D. AGUSTIN, G. RIMA, H. GORNITZKA, J. BARRAU
Inorg. Chem., 39, 5492-5495 (2000)
52
Transition metal complexes of (Schiff base)divalent group 14 element species
[(Salen)M]n=M’(CO)6-n (n = 1, 2; M = Ge, Sn, Pb; M' = Cr, W)
D. AGUSTIN, G. RIMA, H. GORNITZKA, J. BARRAU
Eur. J. Inorg. Chem., 693-702 (2000)
51
Second generation of a polypyridine ligand to mimic enzymes containing nonheme iron centers
C. HEMMERT, A. P. MAESTRIN, M. RENZ, H. GORNITZKA, B. MEUNIER
C. R. Acad. Sci., Sér. IIc, Chim., 735-741 (2000)
50
Synthesis, structure, and reactivity of a 1σ4,3σ2-diphosphaallene
T. KATO, H. GORNITZKA, A. BACEIREDO, G. BERTRAND
Angew. Chem. Int. Ed. Engl., 39, 3319-3321 (2000)
49
Espèces tricoordinées du groupe 14 à ligand base de Schiff. (Base de Schiff)M=E
(M = Ge, Sn ; E = N-SiMe3, S, Se)
D. AGUSTIN, G. RIMA, H. GORNITZKA, J. BARRAU
Main Group Met. Chem., 22, 703-711 (1999)
48
Preparation, X-ray crystal structure, electrical and optical properties of a new
BETS charge transfer salt: κ-(BETS)4Cu2Cl6
T. COURCET, I. MALFANT, H. GORNITZKA, P. CASSOUX, H. KOBAYASHI
Synthetic Metals, 102, 1761-1762 (1999)
47
Structural control in the formation of multidecker sandwich anions of plumbocene:
the effects of encapsulating the alkali metal counterions
M.A. BESWICK, H. GORNITZKA, J. KÄRCHER, M.E.G. MOSQUERA, J.S. PALMER,
P.R. RAITHBY, C.A. RUSSELL, D. STALKE, A. STEINER, D.S. WRIGHT
Organometallics, 18, 1148-1153 (1999)
46
Influence of the anion of FeIII salts on the product distribution in the oxidative
degradation of a tetrapyridyl ligand
M. RENZ, C. HEMMERT, H. GORNITZKA, B. MEUNIER
New J. Chem., 23, 773-776 (1999)
45
Stable heterocyclic (Schiff base) divalent group 14 element species M-O-Schiff
base-O- (M = Ge, Sn, Pb)
D. AGUSTIN, G. RIMA, H. GORNITZKA, J. BARRAU
J. Organomet. Chem., 592, 1-10 (1999)
44
Free and supported phosphorus ylides as strong neutral Brφnsted bases
S. GOUMRI, O. GUERRET, H. GORNITZKA, J.-B. CAZAUX, D. BIGG, F. PALACIOS,
G. BERTRAND
J. Org. Chem., 64, 3741-3744 (1999)
43
Synthesis, characterization and dynamic behavior of mono- and dinuclear
palladium(II) carbene complexes derived from 1,1’methylenebis(4-alkyl-1,2,4triazolium) diiodides
G. BERTRAND, E. DIEZ-BARRA, J. FERNANDEZ-BAEZA, H. GORNITZKA, A. MORENO,
A. OTERO, R.I. RODRIGUEZ-CURIEL, J. TEJEDA
Eur. J. Inorg. Chem., 1965-1971 (1999)
42
The dramatic influence of diamidoamine ligands on the structure and reactivity of
low-valent tin and bismuth derivatives
J.-L. FAURE, H. GORNITZKA, R. REAU, D. STALKE, G. BERTRAND
Eur. J. Inorg. Chem., 2295-2299 (1999)
41
The deprotonated iminophosphorane o-C6H4PPh2P = NSiMe3 as a novel chelating
ligand in organocopper(I) and –zinc(II) chemistry
S. WINGERTER, H. GORNITZKA, G. BERTRAND, D. STALKE
Eur. J. Inorg. Chem., 173-178 (1999)
40
Tungsten carbonyl complexes of 1H-diphosphirenes and diphosphirenylium salts
D. BOURISSOU, Y. CANAC, H. GORNITZKA, C.J. MARSDEN, A. BACEIREDO,
G. BERTRAND
Eur. J. Inorg. Chem., 1479-1488 (1999)
39
Synthesis, characterization and crystal structures of copper(II) complexes
containing multidentate polypyridine ligands
C. HEMMERT, M. RENZ, H. GORNITZKA, B. MEUNIER
Dalton Trans., 3989-3994 (1999)
38
Triflates de (8-méthoxynaphtyl)silyle : voie d'accès à de nouveaux siloxanes
fonctionnels
A. CASTEL, P. RIVIÈRE, F. COSLEDAN, H. GORNITZKA
C. R. Acad. Sci., Sér. IIc, Chim., 221-228 (1999)
37
Chiral Stilbazolium Chromophores: An Approach toward Multiproperty Materials
Combining Conductivity and Second-Order Optical Nonlinearities
R. ANDREU, I. MALFANT, P.G. LACROIX, H. GORNITZKA, K. NAKATANI
Chem. Mater., 11, 840-848 (1999)
36
Preparation and crystal structures of manganese, iron, and cobalt complexes of the
bis[di(2-pyridyl)methyl]amine (bdpma) ligand and its oxidative degradation
product 1,3,3-tris(2-pyridyl)-3H-imidazo[1,5-a]pyridin-4-ium (tpip); origin of the
bdpma fragility
C. HEMMERT, M. RENZ, H. GORNITZKA, S. SOULET, B. MEUNIER
Chem. Eur. J., 5, 1766-1774 (1999)
35
Ligand properties of 1H-diphosphirenes and diphosphirenylium salts towards iron
carbonyl fragments
D. BOURISSOU, Y. CANAC, H. GORNITZKA, A. BACEIREDO, G. BERTRAND
Chem. Commun., 1535-1536 (1999)
34
Synthetic utility of stable phosphanylcarbenes: synthesis and crystal structure of an
α-(lithiomethylene)phosphorane
S. GOUMRI-MAGNET, H. GORNITZKA, A. BACEIREDO, G. BERTRAND
Angew. Chem. Int. Ed. Engl., 38, 678-680 (1999)
33
The electrophilic behavior of stable phosphanylcarbenes towards phosphorus lone
pairs
S. GOUMRI-MAGNET, O. POLISCHUCK, H. GORNITZKA, C. J. MARSDEN,
A. BACEIREDO, G. BERTRAND
Angew. Chem. Int. Ed. Engl., 38, 3727-3729 (1999)
32
New types of stable aldehydes: formylphosphane and formylphosphane oxide
D. AMSALLEM, H. GORNITZKA, A. BACEIREDO, G. BERTRAND
Angew. Chem. Int. Ed. Engl., 38, 2201-2203 (1999)
31
2-π- and 3-π-electron diphosphorus-containing 3-membered heterocycles
Y. CANAC, D. BOURISSOU, H. GORNITZKA, W.W. SCHOELLER, A. BACEIREDO,
G. BERTRAND
Phosphorus sulfur silicon relat. elem., 144-146, 37-40 (1999)
30
Halides of o-substituted aryl-aluminum compounds with coordination numbers
four and five
C. BÖKER, M. NOLTEMEYER, H. GORNITZKA, B. O. KNEISEL, M. TEICHERT,
R. HERBST-IRMER, A. MELLER
Main Group Met. Chem., 21, 565-579 (1998)
29
Isolation of a benzene valence isomer with one-electron phosphorus-phosphorus
bonds
Y. CANAC, D. BOURISSOU, A. BACEIREDO, H. GORNITZKA, W.W. SCHOELLER,
G. BERTRAND
Science, 279, 2080-2082 (1998)
28
The first stable arsaphosphaallene, ArP=C=AsAr
H. RANAIVONJATOVO, H. RAMDANE, H. GORNITZKA , J. ESCUDIE, J. SATGE
Organometallics, 17, 1631-1633 (1998)
27
Synthesis and X-ray crystal structure of bis(germyl)carbodiimides. Spectroscopic
characterization of (hydrogeno)(germyl)cyanamides
M. DAHROUCH, M. RIVIERE-BAUDET, H. GORNITZKA, G. BERTRAND
J. Organomet. Chem., 562, 191-195 (1998)
26
Apparent 1,2-silyl migrations in aromatic carbenes occur by intermolecular silyl
exchanges
S. SOLE, H. GORNITZKA, O. GUERRET, G. BERTRAND
J. Am. Chem. Soc., 120, 9100-9101 (1998)
25
The inferior p-donor ability of phosphanyl versus amino substituents:
consequences on the stability and reactivity of phosphanyl- and aminocarbenes
S. GOUMRI, Y. LERICHE, H. GORNITZKA, A. BACEIREDO, G. BERTRAND
Eur. J. Inorg. Chem., 1539-1542 (1998)
24
Group-13 metal-induced coordination variation of the bis(2-pyridyl)amide ligand
in solution and in the solid state
H. GORNITZKA, D. STALKE
Eur. J. Inorg. Chem., 311-317 (1998)
23
The versatile behavior of a 1,2λ5-azaphosphete towards protic nucleophiles
G. BOUHADIR, K. BIEGER, P. LIVOTTO, R. RÉAU, H. GORNITZKA, F. DAHAN,
G. BERTRAND
J. Organomet. Chem., 529, 79-85 (1997)
22
1,2,4-Triazol-3,5-diylidene : a building block for organometallic polymer synthesis
O. GUERRET, S. SOLE, H. GORNITZKA, M. TEICHERT, G. TRINQUIER, G. BERTRAND
J. Am. Chem. Soc., 119, 6668-6669 (1997)
21
1σ4,2σx-diphosphetes (x=2-6) : on the persistence of the P-P bond
M. SANCHEZ, R. RÉAU, H. GORNITZKA, F. DAHAN, M. REGITZ, G. BERTRAND
J. Am. Chem. Soc., 119, 9720-9728 (1997)
20
The stable (phosphino)(silyl)carbene as a Useful building block: synthesis and
reactivity of 2-phosphorous substituted 2H-azirenes
V. PIQUET, A. BACEIREDO, H. GORNITZKA, F. DAHAN, G. BERTRAND
Chem. Eur. J., 3, 1757-1764 (1997)
19
Products of the Reactions of 2-Diazomalonate and of 2-Diazoindanedione with
Germylenes and Stannylenes
G. OSSIG, A. MELLER, S. FREITAG, O. MÜLLER, H. GORNITZKA, R. HERBST-IRMER
Organometallics, 15, 408-414 (1996)
18
Syntheses, Structures and Reactivity of a Series of (Pentamethylcyclopentadienyl)molybdenum(V)- and tungsten(V) Imido Complexes
K. KÖHLER, H.W. ROESKY, A. HERZOG, H. GORNITZKA, A. STEINER, I. USÓN
Inorg. Chem., 35, 1773-1777 (1996)
17
Structure and Reactivity of [{Te(NMe2)2}∞]; Application to the Preparation of
Metalloorganic Tellurium(II) compounds
R.E. ALLAN,H. GORNITZKA, J. KÄRCHER, M.A. PAVER, M.-A. RENNIE, C.A. RUSSEL,
P.R. RAITHBY, D. STALKE, A. STEINER, D.S. WRIGHT
Dalton Trans., 1727-1730 (1996)
16
Dimers of THF Solvated Lithium Anilide and Lithium Pentafluoranilide - Basic
Building Blocks of Lithium Amide Ladder Structures
R. V. BÜLOW, H. GORNITZKA, T. KOTTKE, D. STALKE
Chem. Commun., 1639-1640 (1996)
15
Synthesis and Characterization of New Dimeric Aminoalanes
T. BELGARDT, J. STORRE, A. KLEMP, H. GORNITZKA, L. HÄMING, H.-G. SCHMIDT,
H.W. ROESKY
Dalton Trans., 3747-3751 (1996)
14
The 2,6-Diisopropyl-phenyl-Groupe as a Bulky Substituent in Boron-Nitrogen
Compounds. II
W. LUTHIN, J.-G. STRATMANN, G. ELTER, A. MELLER, A. HEINE, H. GORNITZKA
Z. Anorg. Allg. Chem., 621(12), 1995-1999 (1995)
13
Synthesis of a Cationic 1,3-Diphospha-2,4-dipallada(II)tricyclo[1.1.1]pentane
Derivative: The First Structurally Characterized Pyramidal Phosphinidene
Y. CANAC, A. BACEIREDO, H. GORNITZKA, D. STALKE, G. BERTRAND
Angew. Chem. Int. Ed. Engl., 34, 2677-2679 (1995)
12
Structural Characterization of Bis[2,4,6-tris(trifluoromethyl)phenyl] and the
Synthesis and Crystal Structure of the Diazadiphosphetidine ((CF3)3C6H2PNC6F5)2
T. LÜBBEN, H.W. ROESKY, H. GORNITZKA, A. STEINER, D. STALKE
Eur. J. Solid State Inorg. Chem., 32, 121-130 (1995)
11
Synthesis and Characterization of Pentafluorphenylamino - Based Amino- and
Iminometallanes. Crystal Structure of (MeAlNC6F5)4 and NHC6F5Ga(MesGa)3(µ3NC6F5)4 (Mes = 2,4,6-Me3C6H2)
T. BELGARDT, S.D. WAEZSADA, H.W. ROESKY, H. GORNITZKA, L. HÄMING,
D. STALKE
Inorg. Chem., 33, 6247-6251 (1994)
10
Coordination of the Bispyridylmethyl Substituent to Group 1 and 13 Metals
H. GORNITZKA, D. STALKE
Organometallics, 13, 4398-4405 (1994)
9
Rearangement and Selective Transmetalation of Bis(pyridyl)methyllithium
H. GORNITZKA, D. STALKE
Angew. Chem. Int. Ed. Engl., 33, 693-694 (1994)
8
Organometallic Titanium Complexes with Unpaired Electrons: Syntheses and
Structures of [{( 5-Cp)2TiF2}3Ti] and [{( 5-Cp )2TiF2}3Al]
F.-Q. LIU, H. GORNITZKA, D. STALKE, H.W. ROESKY
Angew. Chem. Int. Ed. Engl., 32, 442-444 (1993)
7
Diferrocenyldichalkogenide: Synthese und Struktur von Bis[(2-(dimethylaminomethyl)ferrocenyl]diselenid
H. GORNITZKA, S. BESSER, R. HERBST-IRMER, U. KILIMANN, F.T. EDELMANN,
K. JACOB
J. Organomet. Chem., 437, 299-305 (1992)
6
Ferrocenliganden in der Lanthanid-Chemie: Chelatstabilisierung des ersten
Diorganyllanthanid(III)-halogenids
H. GORNITZKA, A. STEINER, D. STALKE, U. KILIMANN, F.T. EDELMANN, K. JACOB,
K.-H. THIELE
J. Organomet. Chem., 439, C6-C10 (1992)
5
Ferrocenhaltige Liganden in der Lanthanid Chemie: Alkoxide und Thiolate
H. GORNITZKA, F.T. EDELMANN, K. JACOB
J. Organomet. Chem., 436, 325-332 (1992)
4
Chelatstabilisierung von Lanthanid(III)-Organylen: Über 2-(Dimethylaminomethyl)ferrocenyl-Komplexe ausgewählter Seltener Erden
K. JACOB, W. KRETSCHMER, K.-H. THIELE, H. GORNITZKA, F.T. EDELMANN,
I. PAVLIK, A. LYCKA, J. HOLECEK
J. Organomet. Chem., 436, 231-240 (1992)
3
Struktur von [Cp*Ru(CO)2]2, (Cp* = η5-Pentamethylcyclopentadienyl)
A. STEINER, H. GORNITZKA, D. STALKE, F.T. EDELMANN
J. Organomet. Chem., 431, C21-C25 (1992)
2
Chelate Stabilization of a Monomeric Lithium Tellurolate
H. GORNITZKA, S. BESSER, R. HERBST-IRMER, U. KILIMANN, F.T. EDELMANN
Angew. Chem. Int. Ed. Engl., 31, 1260-1261 (1992)
1
Neodym(III)komplexe mit stark raumerfüllenden Cyclopentadienyl- und Benzoamidinat-Liganden: Ein Vergleich
A. RECKNAGEL, F. KNÖSEL, H. GORNITZKA, M. NOLTEMEYER, F.T. EDELMANN,
U. BEHRENS
J. Organomet. Chem., 417, 363-375 (1991)
International patents:
B1
Catalyseurs de polymérisation possédant un lanthanide et un ligand tridentate
A. DUMITRESCU, H. GORNITZKA, B. MARTIN-VACA, D. BOURISSOU, G. BERTRAND, J.B.
CAZAUX
Demande européenne n° 99 401 584.0 (25 juin 1999)
Demande internationale : PCT/FR00/01752 (23 juin 2000), publiée sous le n°
WO01/00630 (4 janvier 2001).
B2
Catalyseurs de polymérisation possédant un élément du groupe 11 ou 12 et un ligand
tridentate
H. NGUYEN, H. GORNITZKA, B. MARTIN-VACA, D. BOURISSOU, G. BERTRAND, J.B.
CAZAUX
Demande européenne n° 99 401 585.7 (25 juin 1999)
Demande internationale : PCT/FR00/01753 (23 juin 2000), publiée sous le n°
WO01/00628 (4 janvier 2001).
B3
Utilisation de stannylènes et de germylènes comme catalyseurs de polymérisation
d'hétérocycles
G. BERTRAND, D. BOURISSOU, J.B. CAZAUX, A. DUMITRESCU, H. GORNITZKA, B.
MARTIN-VACA
Demande européenne n° 00401309.0 (15 mai 2000)
Demande internationale : PCT/FR01/01405 (10 mai 2001), publiée sous le n°
WO01/88014 (22 novembre 2001).
B4
Utilisation de dérivés du zinc comme catalyseurs de polymérisation d'esters cycliques
J.B. CAZAUX, G. BERTRAND, A. DUMITRESCU, H. GORNITZKA, D. BOURISSOU, B.
MARTIN-VACA
Demande européenne n° 1 400 926.0 (10 avril 2001)
Demande internationale : PCT/FR02/01220, publiée sous le n° WO02/083761 (24
octobre 2002).